PREPARATION OF POLYMER—SUPPORTED RCpCpTiCl2 AND APPLICATION IN CATALYTIC ISOMERIZATION OF 1,5

摘要 Polymer-supportedRCpCpTiCl2(Cp=η^5-C5H4;RCp=η^5-RC5H4)havebeenpreparedandreducedbyi-C3H7MgBrinsitu，thenusedincatalyticisomerizationof1,5-hexadiene.Theisomerizationof1,5-hexadieneleadstoamixtureofcyclicandlinearproducts.Theratioofcyclictolinearproductdependsonthenatureofthesupporterandthesubstituentonthecyclopentadienylring.Theformercontributesthemost,forexample,silicasupportedCp2TiCl2gavecyclic-linearratioof99/1,whileforpolymer-supportedCp2TiCl2species,linearcompoundsarethemajorproductsandtheratioofcyclictolinearproductchangeswithdifferentRgroupsonthecyclopentadienylring.

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PREPARATION OF POLYMER—SUPPORTED RCpCpTiCl2 AND APPLICATION IN CATALYTIC ISOMERIZATION OF 1,5—HEXADIENE

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PREPARATION OF POLYMER—SUPPORTED RCpCpTiCl2 AND APPLICATION IN CATALYTIC ISOMERIZATION OF 1,5—HEXADIENE

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