摘要
Threeheterobinuclearcomplexesweresynthesized,namely[Cu(oxpn)Co(L)2](ClO4)2·xH2O(L=2,2’-bipyridyl(bpy),1,10-phenanthroline(phen),and5-nitro-1,10-phenanthroline(NO2-phen)),whereoxpnrepresentsN,N’-bis(3-aminopropyl)oxam-ido.Basedon1R,elementalanalysis,conductivitymeasurementandelectronicspectra,thesecomplexeswerecharacterizedbyanextendedoxamido-bridgedstructurewithCu(Ⅱ)inaplanarenvironmentandCo(Ⅱ)inaoctahedralenvironment.ThesymmetryofthecationisveryclosetoC2v.Thecomplexeswerealsocharacterizedwithvariabletemperature(4~300K)magneticsusceptibility,andthedatawerefitforthesusceptibilityequationderivedfromspinHamilton,H=-2JS1.S2-DSx12byleastsquarestrategy.Theexchangeintegral,J,wasfoundtobe-22.36cm-1(forbpy);-15.45cm-1(forphen);-19.10cm-1(forNO2-phen),indicatingthatthereisaweakantiferromagneticspin-exchangeinteractionbetweenthemetalions.
出版日期
1990年04月14日（中国期刊网平台首次上网日期，不代表论文的发表时间）
