摘要
Methyl3-hydroxypropanoatewassynthesizedviahydroesterificationofethyleneoxidewithCOinthepresenceofdicobaltoctacarbonylcatalystandmethanolsolvent.Thecatalystexhibitedhighcatalyticactivity.Theeffectofreactiontemperature,COpressure,methanoldosage,catalystdosageandreactiontimeoncatalyticreactionwasinvestigated.Thetestresultsrevealedthatthisreactionwasgreatlyaffectedbyreactiontemperature,butitwasnotsignificantlyaffectedbytheCOpressure,themethanoldosage,thecatalystdosageandthereactiontime.Undertheoptimalconditions,theconversionofethyleneoxidewasequalto92.24%,whiletheselectivityandyieldofmethyl3-hydroxypropanoatereached88.99%and84.35%,respectively.
出版日期
2012年04月14日（中国期刊网平台首次上网日期，不代表论文的发表时间）
