The reaction of perfluoroalkanesulfinates——Ⅶ.Fenton reagent-initiated addition of sodium perfluoroalkanesulfinates to alkenes-中国期刊网

摘要 Theadditionofsodiumperfluoroalkanesulfinates（RFSO2Na）tovariousolefins（CH2=CHR）initiatedbyFentonreagent(Fe2+-H2O2)inthepresenceofsodiumazidegavetheadduetsRFCH2-CHN3Ringoodyield.AradicalmechanismwasproposedbasedontheEPRandotherevidences.TheadductswerereadilyreducedthroughcatalytichydrogenationtogivethecorrespondingaminesRFCH2CH（NH2）Rinhighyield.Thereactionrepresentsaconvenientandeffectiveroutetotheseusefulorganofluorinecompounds.

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The reaction of perfluoroalkanesulfinates——Ⅶ.Fenton reagent-initiated addition of sodium perfluoroalkanesulfinates to alkenes

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The reaction of perfluoroalkanesulfinates——Ⅶ.Fenton reagent-initiated addition of sodium perfluoroalkanesulfinates to alkenes

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