摘要
Extractionoftitanium(Ⅳ)fromrealchlorideleachliquorofilmenitewascarriedoutwith0.1molL~(-1)di-(2-ethylhexyl)phosphoricacid(HDEHP)inkerosene.EquilibriumandkineticsstudiesforTi(Ⅳ)werecarriedoutinthepresenceofimpuritiesthatwereleachedwithTi(Ⅳ).ParametersaffectingextractionrateofTi(Ⅳ)fromchloridemediainthepresenceofFe(Ⅲ),Mg(Ⅱ),andAl(Ⅲ)werestudiedtoevaluatethestoichiometryofextractedTi(Ⅳ)species.ItisfoundthattheextractionrateofTi(Ⅳ)isdependentontheextractantconcentrationandpHofsolution.Undertheoptimumconditions,morethan95%Ti(Ⅳ)canbeextracted.Onthebasisofslopeanalysismethod,theextractedspeciesofTi(Ⅳ)appearstobe[TiO(H_2A_2)_2]_(org),whereH_2A_2referstoHDEHP.Further,thekineticstudiesoftheextractionprocessofTi(Ⅳ)andothermetalionimpuritieswerecarriedoutbyaLewiscellwithaconstantinterfacialareaof16.7cm~2.AnalysisoftheexperimentalresultssuggeststhatTiO~(2+)extractionratebyHDEHPisthefirstwithrespecttohydrogenionconcentrationandHDEHPconcentration.Theresultsareinterpretedbyareactionmechanismwheretheextractionprocessiscontrolledbyadiffusionprocessattheinterfaceratherthaninthebulkphase.
出版日期
2017年08月18日（中国期刊网平台首次上网日期，不代表论文的发表时间）
