学科分类
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94 个结果
  • 简介:AseriesofCd1-xZnxS/K2La2Ti3O10compositesweresynthesizedviaasimpleco-precipitationmethod.ThepreparedsampleswerecharacterizedbyX-raydiffraction(XRD),scanningelectronmicroscopy(SEM),X-rayenergydispersivespectroscopy(EDX),ultraviolet-visiblediffusereflection(UV-Vis),X-rayphotoelectronspectroscopy(XPS)andphotoluminescence(PL)measurements.ThecompositestructuresconsistedofCd1-xZnxSnanoparticlesevenlydistributedonthesurfaceofK2La2Ti3O10.TheabsorptionedgeofK2La2Ti3O10shiftedtothevisiblelightregionuponintroductionoftheCd1-xZnxSnanoparticles.Thephotocatalyticactivitiesofthecatalystswereevaluatedbyhydrogenproductionundervisiblelightirradiation.ThepreparedCd0.8Zn0.2S(30wt%)/K2La2Ti3O10exhibitedhigherphotocatalyticactivity,evolving6.92mmol/gH2undervisiblelightirradiationfor3h.ThepromotedphotocatalyticactivityofthecompositeswasattributedtothesynergisticeffectbetweenCd1-xZnxSandK2La2Ti3O10,whichresultedinenhancedseparationofphotogeneratedelectronsandholes.

  • 标签: Cd1-xZnxS/K2La2Ti3O10 COMPOSITES PHOTOCATALYSIS hydrogen evolution WATER
  • 简介:近日,国际学术刊物《自然纳米技术》发表了南开大学化学学院高分子化学研究所史林启教授与美国加州大学洛杉矶分校卢云峰教授等多个课题组合作完成的项目成果。该成果研究了一种具有解酒保肝作用的纳米复合酶,可治疗和预防酒精中毒,让醉酒者在十几分钟内恢复清醒。

  • 标签: 解酒 南开大学化学学院 美国加州大学 纳米技术 化学研究所 学术刊物
  • 简介:Themicrostructureofthelasermelted1.0%Ctoolsteelhavebeeninvestigated.Theregionaffectedbythelasercanbesubdividedinto3zones,whichconsistofameltedregionatthesurface,azonewithsolidstatetransformationandtheareaadjacenttotheunaffectedsubstratewherecementiteisslightlydissolved.Themeltedzonepossessedacellulargrowthmorphologyconsistingofausteniteandmartensite.Thecarboncontentoftheaustenitewasmeasuredtobeover1wt-%.Agreatdealofretainedausteniteandtwinnedmartensitewerefoundinthefirsttwozones(themeltedandsolidtransformed).

  • 标签: LASER PROCESS MICROSTRUCTURE melted ZONES
  • 简介:Layeredcathodematerialsofhigh-temperaturelithiumbatteries,LiNi1/3Mn1/3Co1/3O2aresynthesizedbyasol-gelmethodwithvariationinfinalsinteringtemperatureforboreholeapplications.Thestructure,morphologyandhigh-temperaturedischargeperformanceoftheseresultingproductsareinvestigatedbyX-RayDiffraction(XRD),scanningelectronmicroscopy(SEM),laserparticlesizeanalysis,galvanostaticandpulsedischarge.Theresultsofstructuralanalysisindicatethatthesamplesinteredat800℃hasthecharacteristicsofgoodcrystallinity,narrowsizedistributionandlargespecificsurfaceareaatthesametime.Thedischargeexperimentsalsoindicatethatthissamplehasthebestelectrochemicalproperties,withthemaximumdischargecapacitiesof314.57and434.14mAh·g-1at200and300℃respectivelyandtheminimumcellinternalresistancesatbothtemperatures.

  • 标签: SINTERING TEMPERATURE ELECTROCHEMICAL properties Li Ni1/3Mn1/3Co1/3O2
  • 简介:用x射线衍射、光学显微镜、扫描电镜和能谱等分析Al-10Ce中间合金的相组成和微观形貌,研究Al-10Ce中间合金对α-铝的变质处理效果及对α-铝的长效性变质和重熔稳定性变质,并与钠盐变质进行了对比。结果表明:Al-10Ce中间合金用量对变质效果的影响很大,Al-10Ce中间合金用量为0.30%左右时达到最佳变质效果,用量少变质效果差,用量过多则形成过变质。用Al-10Ce中间合金对α-铝进行变质,可取得极好的变质效果,变质持续时间比钠盐变质剂更长久且具有更好的重熔稳定性。

  • 标签: AL-10CE中间合金 变质效果 长效性变质 重熔变质
  • 简介:Anovelfluorescentprobe9-(4-(1,2-diamine)benzene-N1-phenyl)acridine(DABPA)wassynthesizedforthedetectionofnitricoxide(NO)andcharacterizedbyIR,1H-NMRandEI-MSspectroscopy.Basedonaphotoelectrontransfermechanism,thefluorescenceintensitiesofDABPAwereinvestigatedwiththedifferentconcentrationsofNO.Undertheoptimalexperimentalconditions,thefluorescenceintensityofDABPAhadagoodlinearrelationship(R2=0.9977)withNOconcentrationintherangefrom1×10-7to1.5×10-6mol/Lwithadetectionlimitof1×10-8mol/L.ThecytotoxicityinducedbyDABPAwasevaluatedbytheMTT(3-(4,5-dimethylthiazol-2-yl)-2,5diphenyltetrazoliumbromide)assayforbiologicalapplication.Furthermore,theprobeDABPAhadalsobeensuccessfullyappliedtoreal-timeimageNOproducedinPC12cellsinthepresenceofL-arginine.

  • 标签: 荧光探针 一氧化氮 苯基 二胺 氮测定 最佳实验条件
  • 简介:美国铝业公司近日重申,预计2013年全球铝业需求将增长7%,并预计氧化铝和铝市场基本上维持平衡。美国铝业公司预计航空航天市场需求将增加9%~10%,汽车市场需求增加1%~4%,包装市场需求增加1%---2%,商业建筑市场需求增加4%---5%,工业燃气涡轮机终端市场需求增加3%~5%。

  • 标签: 航空航天 美国铝业公司 市场需求 燃气涡轮机 商业建筑 预计
  • 简介:One-dimensional(1D)nanomaterialsandnanostructureshavereceivedmuchattentionduetotheirpotentialinterestforunderstandingfundamentalphysicalconceptsandforapplicationsinconstructingnanoscaleelectricandoptoelectronicdevices.Zincsulfide(ZnS)isanimportantsemiconductorcompoundofII-VIgroup,andthesynthesisof1DZnSnanomaterialsandnanostructureshasbeenofgrowinginterestowingtotheirpromisingapplicationinnanoscaleoptoelectronicdevices.Thispaperreviewstherecentprogresson1DZnSnanomaterialsandnanostructures,includingnanowires,nanowirearrays,nanorods,nanobeltsornanoribbons,nanocables,andhierarchicalnanostructuresetc.Thisarticlebeginswithasurveyofvariousmethodsthathavebeendevelopedforgenerating1Dnanomaterialsandnanostructures,andthenmainlyfocusesonstructures,synthesis,characterization,formationmechanismsandopticalpropertytuning,andluminescencemechanismsof1DZnSnanomaterialsandnanostructures.Finally,thisreviewconcludeswithpersonalviewstowardsfutureresearchon1DZnSnanomaterialsandnanostructures.

  • 标签: 纳米材料 一维结构 硫化锌 纳米结构
  • 简介:ThetransportpropertiesintheLa2/3(Ca1-xSrx)1/3MnO3(x=0,1/3,2/3)filmspreparedusingtheRFmagnetronsputteringmethodwereinvestigated.TheeffectoftheCa,Srdouble-dopingattheApositionintheLa2/3A1/3MnO3onthestructureofthetargetsandtransportofthefilmshasbeenstudied.Withtheincreaseofx,thestructuresofthetargetstransformfromtherhombohedralphasetothecubicphase;themetal-insulatorphasetransitiontemperature(Tp)ofthefilmsincreases;andthecorrespondingpeakresistivitydecreases.Allthephenomenacanbequalitativelyexplainedbythelatticeeffect.

  • 标签: 格子效应 传输性质 氧化锰薄膜 电子喷射 磁致电阻
  • 简介:从5月开始,我国将调整部分商品进出口关税税率,其中锰原矿的出口关税由目前的10%提高至15%。

  • 标签: 进出口 关税 原矿 金属 镍铬