简介:ThemicrostructuresoftheSaxidomuspurpuratusshellwereobserved.Itwasfoundthattheinnerandmiddlelayersoftheshellarecomposedofcrossedlamellae,whiletheouterlayerexhibitsporousstructures.Withthecharacteristicstructureofeachlayer,thehardnessofinnerlayerwithnarrowdomainsincrossedlamellarstructureisthehighest,andthatofmiddlelayerwithwidedomainsislower,whiletheouterlayerhasthelowesthardness.Thedamagemorphologiesoftheindentationschangealot,dependingnotonlyuponthemagnitudeoftheindentationload,butalsoupontheorientationbetweentheindentationdirectionandthecrossedlamellaeinthemicrostructureoftheshell,whichillustratestheanisotropyinmechanicalpropertiesofsuchshells.
简介:碳nanofibers(CNF)的表面functionalization被执行,ie,CNF第一被氧化然后表面经由一个集会方法是由3-Aminopropyltriethoxysilane(APTES)的silanized。一种新类型高穿抵抗s-CNFs/epoxy合成被制作由在原处反应。FTIR光谱学被用来检测silane在CNF的表面上生产的功能的组的变化。tribological性质和微观结构修改,未修改的CNFs/epoxycomposites分别地被学习。expremental结果显示APTEScovalently成功地被连接到CNF的表面并且在环氧基树脂矩阵改进CNF的分散。磨擦系数和s-CNFs/epoxycomposites的wear率是比在一样的负担下面的u-CNFs/epoxycomposites的那些显然低的。调查也显示磨料穿主要为u-CNFs/epoxy穿机制合成,为在一样的滑动下面合成的s-CNFs/epoxy与细微粘合剂穿穿状况。
简介:λ-MnO2waspreparedbycolumnmethodfromnormalspinelLiMn2O4withpurityof99.38%.TheinfluenceofLiMn2O4grainsizeandacidityofleachingsolutiononthelithiumleachingprocesswasstudied.TheresultsshowthattheappropriaterangeofLiMn2O4grainsizewas60-160meshesandtheconcentrationofleachingsolutionHClwas0.1mol·L-1.TheadsorptioncapacityQofλ-MnO2forlithiumincreasedwiththeincreaseofpHandchangedmarkedlyatpH6.0-10.0.Itwas3.80mmol/gatpH12.0.ThedistributioncoefficientsKdofLi+andNa+were3.406×104and2.300respectively,andtheseparationcoefftcientaLiNawas1.481×104atpH6.5.Asaresult,λ-MnO2isahighperformanceion-sievematerialforlithiumion.
简介:Theelectronicstructureandbondingnatureofaseriesofcollectorsinthecalciumandmagnesiumcontainingmineralssystemarestudiedusingquan-tumchemistryCNDO/2method.Thedifferenceincol-lectingpropertiesisdiscussedbymeansofcharac-teristicparametersderivedfromthequantumchem-istrycalculations,andthedevelopingdirectionoffattyacidcollectorsispredicted.
简介:有公式La9.33Si6O26的磷灰石类型镧硅酸盐被大音阶的第五音胶化过程准备。答案的pH价值影响的大音阶的第五音的同质被调查。大音阶的第五音的粘性稍微增加第一然后因为占优势的反应机制从水解作用反应改变到冷凝作用反应,突然地增加。另外,为粘性的增加的发作时间从pH弄短1到pH4。冻结时间与增加答案的pH减少。因此,大音阶的第五音的pH应该是不到4形成胶化。有起始的pH的大音阶的第五音希腊语的第六个字母潜力和最大的稳定性的2表演最大值价值。为有起始的pH的样品2,在弄干的胶化被锻烧在以后,纯磷灰石类型镧硅酸盐La9.33Si6O26成功地被准备了1000
简介:Althoughin-situgrowingcarbonnanotubes(CNTs)oncarbonfiberscouldgreatlyincreasethematrix-dominatedmechanicalpropertiesofcarbon/carboncomposites(C/Cs),italwaysdecreasedthetensilestrengthofcarbonfibers.Inthiswork,CNTswereintroducedintounidirectionalcarbonfiber(CF)preformsbyelectrophoreticdeposition(EPD)andtheywereusedtoreinforceC/Cs.EffectsofthecontentofCNTsintroducedbyEPDontensilepropertyofunidirectionalC/Cswereinvestigated.ResultsdemonstratedthatEPDcouldbeusedasasimpleandefficientmethodtofabricatecarbonnanotubereinforcedC/Cs(CNT—C/Cs)withexcellenttensilestrength,whichpaysameaningfulwaytomaximizetheglobalperformanceofCNT—C/Cs.
简介:Silicide涂层被泥浆包硬化进程为把SiO2用作纯艾尔Si来源的12h在1173K在铜矩阵上在electro-deposited镍层上作好准备作为reducer搽粉,NaF+NH4Cl和蛋白(鸡蛋白人)是连贯的代理人。微观结构,性质和silicide涂层的siliconizing机制被讨论。有220μm厚度的silicide涂层主要是的试验性的结果表演Ni2Si阶段和Ni31Si12阶段。它的吝啬的微坚硬(HV790)比铜底层(HV70)的是十次。磨擦的系数从0.8纯铜减少到大约0.3硅Z样品。SiF2,SiCl2和SiCl3在泥浆包装硬化过程期间为Si的交通和免职负责。
简介:设计象建筑学,孔,机械性质和表面性质那样的脚手架的骨头织物的性质在细胞的反应上有重要效果并且在骨头新生起一个重要作用。在这研究,threedimensionalnanocomposite脚手架由钙磷酸盐(帽子)组成nanoparticles并且poly(hydroxybutyrate-co-hydroxyvalerate)(PHBV)共聚物与控制了外部、内部的体系结构成功地经由选择激光sintering(SLS)被生产,万用的快速的原型技术之一。Ca-P/PHBVnanocomposite脚手架有一个孔(对类脂化合物peroxidation的61.75ct。他们的IC50价值是196和273牯敭吗?
简介:Anovelsolubleπ-conjugatedpolymer,poly[(3-acetylpyrrole-2,5-diyl)p-(N,N-dimethylamino)azobenzylidene](PAPDMAABE),wassynthesizedbycondensationof3-acetylpyrrolewith4-aldehyde-4'-dimethylaminoazobenzene(ADMAA).ThechemicalstructureofPAPDMAABEwascharacterizedbyFouriertransforminfraredspectroscopy(FTIR),1H-NMR,andUV-Vis-NIRspectra.Transmissionelectronmicroscope(TEM)analysisforPAPDMAABEindicatesthatpartofPAPDMAABEisincrystalstate,duetotheshort-rangeorderofthepolymer.Thermogravimetricanalysis(TGA)curveshowsthatthepolymerhasgoodthermalstabilityanditsdecompositiontemperatureis248℃.TheopticalbandgapofPAPDMAABEobtainedfromtheopticalabsorptionspectrumisabout1.73eV.Theresonantthird-ordernonlinearopticalpropertyofPAPDMAABEat532nmwasstudiedusingdegeneratefour-wavemixing(DFWM)technique.Theresonantthird-ordernonlinearopticalsusceptibilityofthepolymerisabout7.48×10-8esu.
简介:ThecompositenanofibersofSrTiO3/SrFe12O19withamolarratioof1:1anddiameterabout120nmwerepreparedbyelectrospinning.Effectsofcalcinationtemperatureontheformation,crystallitesize,morphologyandmagneticpropertywerestudiedbyinfraredspectroscopy,X-raydiffraction,scanningelectronmicroscopyandvibratingsamplemagnetometer.Thebinaryphaseofstrontiumferriteandtitanatewasformedafterbeingcalcinedat900℃for2handthecompositenanofiberswerefabricatedfromnanograinsofSrTiO3about24nmandSrFe12O19around33nm.ThecrystallitesizesforthenanofibersincreasewithincreasingcalcinationtemperatureandtheadditionofSrTiO3hasanobvioussuppressioneffectonSrFe12O19graingrowth.Thespecificsaturationmagnetizationandremanencetendtoincreasewiththecrystallitesize.Withincreasingcalcinationtemperaturefrom900to1050℃,thecoercivityincreasesinitially,achievingamaximumvalueof520.2kA·m-1at950℃,andthenshowsareductiontendency.