简介:ThediamondfilmsadherenttoSisubstratearedepositedwiththemicrowaveplasmaCVD(MPCVD)atmicrowavepowersof6000Wand4000Wfrom6hto10h,respectively,theinternalstressesofthefilmsaremeasuredbyXRD.Spectralpeakshiftandwideningareappliedtocalculatethemagnitudesofmacroandmicrostresses.Theresultsshowthatthemacrostressistensile.Theinternalstresscanbecontrolledbythemicrowavepower.Withthemicrowavepowerincreasing,theintrinsicandmacrostressesdecrease,andthemicrostressincreasessignificantly.Also,itcanbefoundthatthemacroandmicrostressesincreasewithdepositedtimewhentheotherconditionsarethesame.
简介:Alargediamondcrystalupto500μmindiameterwithasmooth(100)facetatitstophasbeensynthesizedonMosubstratethroughmicrowaveplasmachemicalvapordeposition(MPCVD).Itsmorphologyandqualitywerecharacterizedbyscanningelectronmicroscopy(SEM),andthegrowthmechanismwasroughlyillustratedfrombothmacroscopicandmicroscopicviewpoints.Itwasfoundthatmorphologicalinstabilitiesareamajorfactorresultinginsynthesisoflargediamondcrystals,moreover,highmicrowavepowerdensity(MPD),highCH4concentrations,highpressure,highsubstratesurfacetemperatureandtheadditionofasmallamountofO2werealsonecessaryforthesynthesisoflargediamondcrystals.