简介：Anewefficientmeshlessmethodbasedontheelement-freeGalerkinmethodisproposedtoanalyzethestaticdeformationofthinandthickplatestructuresinthispaper.Usingthenew3Dshell-likekinematicsinanalogytothesolid-shellconceptofthefiniteelementmethod,discretizationiscarriedoutbythenodeslocatedontheupperandlowersurfacesofthestructures.Theapproximationofallunknownfieldvariablesiscarriedoutbyusingthemovingleastsquares(MLS)approximationschemeinthein-planedirections,whilethelinearinterpolationisappliedthroughthethicknessdirection.Thus,differentboundaryconditionsaredefinedonlyusingdisplacementsandpenaltymethodisusedtoenforcetheessentialboundaryconditions.TheconstrainedGalerkinweakform,whichincorporatesonlydisplacementdegreesoffreedom(d.o.f.s),isderived.Amodified3Dconstitutiverelationshipisadoptedinordertoavoidoreliminatesomeself-lockingeffects.Thenumericefficiencyoftheproposedmeshlessformulationisillustratedbythenumericexamples.

简介：TiO2@ZrO2@Y2O3:有coremultishell结构的Eu3+合成粒子通过layer-by-layer(LBL)的联合被综合自己组装方法和一个solgel过程。获得的样品与扫描电子被描绘显微镜学(SEM)，传播电子显微镜学(TEM)，X光检查光电子光谱学(XPS)，X光检查衍射(XRD)，和荧光spectrophotometry。结果证明合成粒子有coremultishell结构，球形的形态学，和狭窄的尺寸分布。TiO2核心上的ZrO2层的存在能有效地阻止在TiO2核心和Y2O3壳之间的反应；为在在TiO2@ZrO2@Y2O3的TiO2核心和Y2O3壳之间的反应的温度:Eucoremultishell黄磷能被300提高

简介：ThisstudypresentsanovelprocessofinsitusurfacemodificationofCaCChnanoparticlesusingamultipleorificedispersionmicroreactor.CO2/Ca（OH）2precipitationreactionwasemployedtoprepareCaCO3nanoparticleswithsodiumstearatesurfactant.SynthesizedCaCChproductswerecharacterizedbythermogravimetricanalysis（TGA）,infra-red（IR）,X-raydiffraction（XRD）,transmissionelectronmicroscopy（TEM）andBrunauer-Emmet-Telleranalysis（BET）.Theeffectofvariousoperationparametersonnanoparticlesandthedosageofsodiumstearateweredetermined.Theresultsshowedthatthepreparationprocesscouldbepreciselycontrolledwithefficientmasstransferprocess.Theparticleswerehighlyhydrophobicwithacontactangleof117andmonodispersewithanaveragesizeof30nm.Theadsorptionsofsodiumstearateandcalciumiononsolidparticlesduringtheinsitusurfacemodificationprocesswereinvestigated.

简介：hard-core/soft-shell钙碳酸盐(CaCO3)的合成/poly(甲基methacrylate)(PMMA)混合结构化的nanoparticles(<100nm)由把分裂成原子的微乳液聚合，过程被报导。聚合物链通过acoupling代理人的使用被抛锚到nano-CaCO3的表面上，triethoxyvinylsilane(TEVS)。铵persulfate(APS)，钠dodecyl硫酸盐(SDS)和n-pentanol分别地被用作开始者，表面活化剂和cosurfactant。coreshell乳胶粒子的聚合机制被讨论。由PMMA的nano-CaCO3的封装用一台传播电子显微镜(TEM)被证实。coreshell粒子的grafting百分比被thermogravimetric分析(TGA)调查。nano-CaCO3/PMMAcoreshell粒子被Fourier变换描绘红外线(FTIR)光谱学和微分扫描热量测定(DSC)。FTIR结果在nano-CaCO3粒子和PMMA的接口揭示了一个强壮的相互作用的存在，它成功地暗示聚合物链是grafted到通过联合代理人的连接的nano-CaCO3粒子的表面上。另外，TGA和DSC结果与纯nano-PMMA的相比显示了coreshell材料的热稳定性的改进。nano-CaCO3/PMMA粒子被混合进聚丙烯(PP)矩阵由融化处理。它能也用扫描PMMA锁住的电子显微镜学(SEM)被观察grafted在聚合物矩阵(PP矩阵)防碍到CaCO3nanoparticles上CaCO3的聚集并且因此与PP矩阵改进CaCO3nanoparticles的相容性。