简介:Aconvenientanddirectper(poly)fluoroalkylmethyl-mtroducingcyclopropanationreactionwasdescribed.InthepresenceofCrCl3/Fe,per(poly)fluoroalkyliodidesreactedwithdiethylallylmalonateanditsanalogstogiveper(poly)fluoroalkylmethyl-substitutedelectrophiliccyclopropanederivativesinhighyields.Thisreactionwasconsideredtoproceedbytwosteps:radicaladditionfollowedbycyclopropanation.
简介:Underdifferentreactionconditions,theexpectedandunexpectedreactionproducts(ofwhichX-raycrystallographicstructurewaspresented)ofetherificationof2-per(poly)fluoroethyl4-substitutedphenolwithβ-haloethanolcanbeobtainedrespectively.