简介:Core-shellstructurednanosphereswithmesoporoussilicashellandNicore(denotedasNi@meso-SiO2)arepreparedthroughathree-stepprocess.MonodispersedNiprecursorsarefirstprepared,andthencoatedwithmesoporousSiO2.FinalNi@meso-SiO2spheresareobtainedaftercalcination.TheproductsarecharacterizedbyX-raypowderdiffraction,transmissionelectronmicroscopyandN2adsorption-desorptionmethods.Thesesphereshaveahighsurfaceareaandarewelldispersedinwater,showingahighcatalyticactivitywithaTOFvalueof18.5,andoutstandingstabilityinhydrolyticdehydrogenationofammoniaboraneatroomtemperature.
简介:有在粒子的核心的高carboxyl内容的没有肥皂的吸水恐水病的核心壳乳胶粒子经由播种乳剂被综合聚合使用甲基methacrylate(MMA),丁基acrylate(BA),甲基丙烯酸(MAA),苯乙烯(圣)和乙烯乙二醇dimethacrylate(EGDMA)作为单体,并且在聚合,粒子尺寸和形态学上在核心准备使用的MMA内容的影响被传播电子显微镜学调查,动态轻散布结果证明播种乳剂聚合能用当在核心准备的MAA内容是时,喂过程的饥饿的单体顺利被执行平等者到或不到24wt%,并且有恐水病的PSt壳的吸水的P(MMA-BA-MAA-EGDMA)核心的包含的效率随MAA内容的增加减少了。当有中等极性的P(MMA-MAA-St)的夹层在P(MMA-BA-MAA-EGDMA)核心和PSt壳之间被插入时,井在核心准备与24wt%MAA内容设计了没有肥皂的吸水恐水病的核心壳乳胶粒子被获得。
简介:Theconceptofcombiningmetallichoneycombwithfoldedthinmetallicsheets(corrugation)toconstructanovelcoretypeforlightweightsandwichstructuresisproposed.Thehoneycomb–corrugationhybridcoreismanufacturedbyfillingtheintersticesofaluminumcorrugationswithprecision-cuttrapezoidalaluminumhoneycombblocks,bondedtogetherusingepoxyglue.Theperformanceofsuchhybrid-coredsandwichpanelssubjectedtoout-of-planecompression,transverseshear,andthree-pointbendingisinvestigated,bothexperimentallyandnumerically.Thestrengthandenergyabsorptionofthesandwicharedramaticallyenhanced,comparedtothoseofasandwichwitheitheremptycorrugationorhoneycombcore.Theenhancementisinducedbythebeneficialinteractioneffectsofhoneycombblocksandfoldedpanelsonimprovedbucklingresistanceaswellasalteredcrushingmodesatlargeplasticdeformation.Thepresentapproachprovidesaneffectivemethodtofurtherimprovethemechanicalpropertiesofconventionalhoneycomb-coredsandwichconstructionswithlowrelativedensities.
简介:TiO_2-coatedpolystyrenenanoparticleswerepreparedinasimpleway.First,functionalPSparticlesweresynthesizedbycopolymerizingonekindofpolymerizablesurfactantwithstyrene.Thenthestabledispersionsofpolystyrenenanoparticleswereusedastemplates,andpolystyrenenanoparticleswerecoatedwithtitaniabyinsituhydrolysisoftetra-n-butyltitanate(TBT).Nosurfacetreatmentandcentrifugation/redispersioncycleprocesswereneededduringthewholeexperiment.IsolatedPSsphereswithuni...
简介:Experimentswereconductedtostudythegenerationofaircoreanditseffectontheoutflowshapeanddischargeinacylindricalwatertankwithabottomwell-designedoutlet.Dependingonthestagesoftheaircoreinthetank,theoutflowshapecanvaryfromasmoothwaterjettoasmoothspindleshapewithair-core,andtowatersprays.Thediameterofthenozzlesizealsohasinfluenceontheoutflowpattern.Theexistenceofthepenetratedaircorecandramaticallyreducetheoutflowdischarge,withthedischargecoefficientdecreasingwiththenozzlediameter.
简介:Thispaperconcernswiththecoreofnonatomicgaxaesoffomaf(μ),whereμisanonatomicnonnegativemeasureandfisacontinuousconvexfunctiononthedomalnofμ.Themainresultofthispaperisthatthecoreofthegameisnotcompactunderthenormtopologyunlessthegameitselfisameasure.ThisshowsthelargenessofthecoreinasenseotherthanthatdefinedbySharkyforfinitecases.
简介:'Giant'CdSe/CdScore/shellnanocrystals(NCs)weresynthesizedwiththickCdSshell(15monolayers),andthex-raydiffraction(XRD)measurementindicatesthereisazincblendephaseinthethickCdSshell,whereasittransformedintowurtzitephaseunder5minradiationwitha400nm,594μJ∕cm2femtosecond(fs)laserbeam.TheevolutionoftheNCs’spontaneousemissionunderthefslaserradiationwasrecordedwithaHamamatsustreakcamera.Theas-synthesizedNCsexhibitanamplifiedspontaneousemission(ASE)at530nm,whichcomesfromabulk-likeCdSshellduetotheinterfacialpotentialbarrier,whichcouldslowdowntherelaxationofholesfromtheshelltothecore.Afterbeingannealedbyanfslaser,theASEoftheg-NCsistransferredfromabulk-likeCdSshelltoaquantum-confinedCdSecorebecausethephasetransformationdeterminedwiththeXRDmeasurementcouldremovetheinterfacialbarrier.BesidestheASEat643nm,twoshorter-wavelengthASEpeaksat589and541nm,correspondingtoopticaltransitionsofthesecond(1P)andthird(1D)electronquantizationshellsoftheCdSecore,alsoappear,thusindicatingthatAugerrecombinationiseffectivelysuppressed.
简介:Thechiralclusters(μ3-S)MCoW(CO)8[η^5-C5H4C(O)OCH3][M=Ru(2),Fe(3)]weresynthesizedbyasymmetricinductionofN-benzylcinchoniumchlorideasphase-transfercatalyst(PTC).ThemostsuitableamountofPTCis70mol%.Cluster3wasdeterminedbysinglecrystalX-raydiffractionanalysis.Thebesteeofthechiralclusterisover20%.
简介:Coremodecutoffisausefulconceptnotonlyforataperedsingle-corefiber(SCF)butalsoforataperedmulticorefiber(MCF)torealizecladdingmodetransmission.Inthispaper,cut-offconditionsofeithercoremodefortaperedSCFsorsupermodesforMCFsaretheoreticallyinvestigated.RigorousanalyticalformulasarederivedforthemodesofSCFbyathree-layerwaveguidemodel,andanapproximationformulaofthecut-offconditionisgivenfortheLP01mode.ThesupermodesofMCFsareanalyzedbythecouplingmodetheory,andthecut-offconditioniscalculatedbyanumericalmethod.Simulationresultsshowthatthein-phasesupermodeofMCFshasasimilarcut-offconditionwiththatofSCF.Basedonthisproperty,aconvenientapproximateformulaisgiventoestimatethecut-offconditionofthein-phasesupermodefortaperedMCFs.
简介:Polystyrene(PS)fiberswithcore-shellstructureswerefabricatedbycoaxialelectrostaticspinning,[10_TD$IF]inwhichthereareliquidepoxyorcuringagentasthecoreandPSastheshell.Scanningelectronmicroscopy(SEM),Fouriertransforminfrared(FTIR)spectraandopticalmicroscopewereutilizedforcharacteringthemorphologyandcompositionofthefibers.Compositecoatingsembeddedwiththehealant-loadedcoreshellfibershavebeenpreparedandtheself-healingofthescratchonthecoatingshasbeenrevealed.
简介:Wereviewtheuseofhollow-corephotoniccrystalfibre(HC-PCF)forhighpowerlaserbeamdelivery.AcomparisonofbandgapHC-PCFwithKagome-latticeHC-PCFonthegeometry,guidancemechanism,andopticalpropertiesshowsthattheKagome-typeHC-PCFisanidealhostforhighpowerlaserbeamtransportationbecauseofitslargecoresize,lowattenuation,broadbandtransmission,single-modeguidance,lowdispersionandtheultra-lowopticaloverlapbetweenthecore-guidedmodesandthesilicacore-surround.ThepowerhandlingcapabilityofKagome-typeHC-PCFisfurtherexperimentallydemonstratedbymillijoulenanosecondlasersparkignitionand~100μJsub-picosecondlaserpulsetransportationandcompression.
简介:界面的脱臼可以有相应于的一个传播核心一弱砍接口的抵抗。在这份报纸,一个圆锥形的模型被建议在各向异性的bimaterials模仿界面的脱臼的传播核心。由Stroh形式主义和草地功能,有弹性的地的分析表达式为如此的脱臼被推出。作为一个例子拿Cu/Nbbimaterial,方法的精确性和效率被接口条件很好验证,这被表明,一个传播核心能极大地与紧缩的核心相比在界面的脱臼附近减少压力紧张,并且传播核心区域附近的有弹性的地与压缩核心显著地不同,当他们对是的一个地点不太敏感时,1.5预定核心宽度离开传播核心的中心。
简介:Wepresentapolarization-maintainingPANDAring-corefiber(PM-PRCF)characterizedbythecombinationofaring-corestructurewithtwostress-applyingrods.Thisspecialfiberdesignseparatestheadjacentmodesandavoidsthecutoffofthehigher-ordermodes,whichisacommonprobleminellipticalcorepolarization-maintainingfew-modefibers.Usingahigh-contrastindexringandstress-inducedbirefringence,thePM-PRCFfeaturessupportfor10vectormodes,witheffectiverefractiveindexseparationsfromtheiradjacentmodes>10-4.Broadbandperformanceisinvestigatedsubsequentlyoverawidewavelengthrangefrom1500to1630nm.Theproposedfiberistargetedatapplicationsinspace-divisionmultiplexingwhileeliminatingthecomplexmultiple-inputmultiple-outputsignalprocessing.
简介:Weproposeanddemonstrateataperedhollowannularcorefiber(HACF)couplerforexcitationofwhisperinggallerymodes(WGMs)ofanembeddedmicrosphereresonator.ThecouplerissimplyfabricatedbyfusionsplicingofasegmentofHACFwiththesingle-modefiber(SMF),andthenimprovedbytaperingthesplicingjointtoreducethecone-apexangle.Therefore,thecouplingefficiencyfromtheSMFtotheHACFisenhancedtoexcitevariousWGMsviaevanescentfieldcoupling.Normalpositive,negativesymmetricalLorentzianandasymmetricFanolineshapescanbeobtainedbyvaryingtheresonatorsizeandlocation.AnotherinterestingphenomenonisobservedthatahigherQ-factormodeinalowerQ-factormodehasacontrastashighas58.Temperaturesensingwithgoodstabilityisalsodemonstrated.ThisembeddedWGMmicrosphereresonatorinthetaperedHACFisexpectedtopromoteenvironmentaladaptabilityinpracticalapplicationsduetoitssimplicityandrobustness.