学科分类
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34 个结果
  • 简介:Resultsobtainedfromthewide-spacedfloodplainsedimentsindicatethattheabundancesofPtandPdinfloodplainsedimentsare0.46ng/gand0.40ng/g,respectively.Threegeochemicalprovinces.Yunnan-Guizhou,Xinjiang-GansuandTibetofPtandPdwithacontentof0.8ng/g,weredelineated.

  • 标签: 富集 地球化学 泛滥平原沉积物 Pt
  • 简介:国际铂金协会(PlatinumGuildInternational简称PGI)是一个国际性非盈利组织,致力于在全球范围内创建、发展并巩固铂金市场,为消费者和珠宝业者提供相关信息、专业知识以及激发消费者对铂金首饰的向往,从而促进产品的开发和销售。

  • 标签: 铂金首饰 国际性 协会 全球范围 相关信息 专业知识
  • 简介:InthispapertheseparationofbasemetalsFe,Co,NiandCufromtheplatinummetalsonacationexchangercolumnwasstudies.Theconvenientseparationconditionsare0.5mol·dm^-3NaCl,pH=2.TherecoveryefficiencyofRhis98%.

  • 标签: 碱金属分离 阳离子交换树脂
  • 简介:Anodesusedfordirectmethanolfuelcells(DMFCs)werefabricatedbymagnetronsputteringprocess.Ahouse-madeplasmasputteringsystemwasusedtodepositPtandPtRuontoun-catalyzedgasdiffusionlayers(GDLs)atdifferentradiofrequency(RF)powersandsputteringgaspressures.ThethinfilmcatalystlayerswerecharacterizedbyX-raydiffraction,energydispersiveX-rayanalysis,andX-rayphotoelectronspectroscopy.Thesputteredanodeswereassembledincustom-mademembraneelectrodeassemblies(MEAs)withacommercialcathodeandtheelectricalperformanceofthesinglecellweretestedunderpassivemethanolsupply,ambienttemperatureandair-breathingconditions.TheelectrochemicalperformanceoftheanodespreparedwithPtRualloywascomparedwithareferenceanodesputteredwithPtonly.X-raydiffractionandX-rayphotoelectronspectroscopyrevealedthatplatinumandrutheniumexistedasaformofalloy.ThecellpolarizationmeasurementsshowedthatallthePtRualloycatalystshadbetterelectrochemicalperformancethanthePt_1catalyst,andthePt_(0.43)Ru_(0.57)catalystachievedthebestperformance.

  • 标签: 直接甲醇燃料电池 磁控溅射工艺 铂催化 阳极 X射线衍射分析 制备
  • 简介:Inthiswork,ultrasonicirradiationanddestabilizersolventwereusedfordestabilizingcolloidalplatinumdispersions.Thestabilizedplatinumnanoparticleswerepreparedinw/omicroemulsionsystemscomposedofsodiumbis-(2-ethylhexyl)sulfosuccinate(AOT)andfourdifferentsolvents,namely,cyclohexane,n-hexane,n-heptane,andn-nonane.TherecoveryprocessofPtnanoparticlesfromthecolloidalsystemswasperformedbyexposingthecolloidalsamplestoultrasonicirradiationandapplyingvariousdestabilizingsolvents.AnalysisofUV-visiblespectraconfirmsthatthequantityofPtnanoparticlesremovedfromthesuspensiondependsonthelengthoftimeoftheultrasonicirradiationandthenatureofthemicroemulsionoilphase.Acriticaltimefortheultrasonicirradiationhasbeenintroducedforthephaseseparationofcolloidalsystems.Toperformthesolventstudy,fourdestabilizersolvents,namely,dioxane,ethylacetate,diethylether,andtetrahydrofuran,wereusedforbreakingthecolloidalsuspensionofplatinumnanoparticles.Basedonthe’goodsolvent’and’poorsolvent’idea,itisverifiedthattheeffectofthedestabilizersolventsontheaggregationprocessfollowsthefollowingorder:tetrahydrofuran>ethylacetate>dioxane>diethylether.

  • 标签: 铂纳米粒子 胶体悬浮液 超声波照射 溶剂效应 纳米颗粒 不稳定
  • 简介:Platinum-basedanticanceragentsarewidelyusedasfirst-linedrugsincancerchemotherapyforvarioussolidtumors.However,greatsideeffectsandoccurrenceofresistanceremainasthemajordrawbacksforalmostalltheplatinumdrugsdeveloped.Toconquertheseproblems,newstrategiesshouldbeadoptedforplatinumdrugbasedchemotherapy.Modernnanotechnologyhasbeenwidelyemployedinthedeliveryofvarioustherapeuticsanddiagnostic.Itprovidesthepossibilityoftargeteddeliveryofacertainanticancerdrugtothetumorsite,whichcouldminimizetoxicityandoptimizethedrugefficacy.Here,inthisreview,wefocusedontherecentprogressinpolymerbaseddrugdeliverysystemsforplatinum-basedcombinationtherapy.

  • 标签: 治疗药物 基础 传递系统 抗癌药物 药物开发
  • 简介:Silica-bound15-Crown-5,18-Crown-6withaspacerofpropyloxymethylandtheirplatinumcomplexeshavebeensynthesized.Itwasfoundthattheywereefficientcatalystsforthehydrosilylationofolefmswithtriethoxysilaneinthetemperaturerangeof60to130℃.

  • 标签: CROWN ETHER SUPPORTED CROWN ETHER PLATINUM
  • 简介:Thepresentpaperrepresentsthesynthesesofpolypropyloxymethyldithia15-crown-5and18-crown-6supportedonsilicaandtheirplatinumcomplexes.Theplatinumcomplexesareeffectivecatalystsforthehydrosilylationofolefinswithtriethoxysilane.Theinfluencesoftemperature,amountofplatinumcomplexesusedandthenatureofolefinsusedonthecatalyticactivityofthecomplexesarealsoinvestigatedinthispaper.

  • 标签: FUNCTIONALIZED POLYSILOXANE Thiacrown ETHER Platinum complex
  • 简介:Silica-boundmercaptoselenaether-containingsilsesquioxaneanditsplat-inumorrhodiumcomplexweresynthesizedfromγ-(2,3-epithiopropyl)propyltrimethoxysi-laneviaring-openingreactionwithbis(2-hydroxyethyl)sclenide,followedbyhydrolysisandimmobilizationonfumedsilica,andthenreactingwithpotassiumchloroplatiniteorrhodiumchlorideinacetoneundernitrogenatmosphere.Itwasfoundthattwonoblemetalcomplexescancatalyzethehydrosilylationofolefinswithtriethoxysilaneeffectively.Theinfluencesoftemperature,theamountofcomplexused,thenatureofolefinoncatalyticactivitywereinvestigated.

  • 标签: POLYMER-SUPPORTED CATALYST HYDROSILYLATION CATALYST PLATINUM RHODIUM
  • 简介:Acrylateterpolymer-boundSe,Nbidentateligandwassynthesizedfromthesidechainchlorineofcopolymerandβ-dimethylamino-β′-hydroxyl-diethylselenoether.Thepolymer-supportedplatinumcomplexexhibitedhighcatalyticactivityinthehydrosilylationofolefinswithtriethoxysilane.

  • 标签: 合成 催化活性 铂络合物 双配位基
  • 简介:IntroductionSelenoetherplatinumcomplexesasanewkindofhydrosilylationcatalysthavebeendrawnmuchatentionrecently.Aseriesofselenoe...

  • 标签: POLYSTYRENE bound CATALYST PLATINUM COMPLEX HYDROSILYLATION
  • 简介:Thechemistryofthethiacrowns,especially,ofthepolymer-supportedthiacrowns,hasnotbeendevelopedtotheextendofthecrownsorazacrowns.Veryfewfunctionalizedthiacrowncompundshavebeenprepared.Nopaperconcerningthepolymer-supportedthiacrownsplatinumcomplexesandtheircatalyticbehaviorhasbeenpublishedyet.Inthispaper,thesynthesisoffumedsilica-supportedpolyundecyloxymethyl-1,4-dithia-7,10,13-trioxacyclopentadecanesiloxaneandsilica-supportedpoly-undecyloxymethyl-1,4-dithia-7,10,13,16-tetraoxacyclooctadecanesiloxane,aswellastheirplatinumcomplexes,andthecatalyticactivityofthecomplexesforthehydrosilylationofolefinswithtriethoxysilanearereported.

  • 标签: 合成 硫冠乙醚铂络合物 聚硅氧烷 催化行为 三乙氧基甲硅烷 聚硅醚
  • 简介:Anewtypeofseleniouspolymer,silica-boundpolybispropoxyethyl-selenidesilsesquioxane,anditsplatinumcomplexweresynthesizedfrombis-allyloxyethylselenideviahydrosily-lationwithtriethoxysilane,followedbyimmobilizedonfumedsilica,andthenreactingwithpotassiumchloroplatiniteundernitrogenatmosphereinacetone.Itwasfoundthattheplatinumcomplexcancatalyzethehydrosilylationofolefinswithtriethoxysilaneeffec-tivelyTheeffectsofthenatureofthesubstrate,theamountofcomplexused,andthereactiontemperatureonthecatalyticactivitywereinvestigated.

  • 标签: Selenaether PLATINUM HYDROSILYLATION CATALYST HYDROSILYLATION POLYSILOXANE
  • 简介:Ru(bpy)_(3~(2+))electrochemiluminescence(ECL)wasappliedtodeterminationofrutin.ECLintensityofRu(bpy)_(3~(2+))couldbeenhancedinthepresenceofrutininbasicsolutiononplatinumelectrode.AtpH9.9,lightemissionintensitywasfoundtobelinearwithrutinintherangeof1-50mmol/L.

  • 标签: 联吡啶钌 电致化学发光 芸香苷 铂电极
  • 简介:在自我组织的TiO2nanotubes(Pt-TiO2/Ti)上支持的铂nanoparticles用cathodic减小跟随的电气化学的阳极的氧化被准备。结构和Pt-TiO2/Tielectrocatalyst的化学自然被X光检查衍射(XRD)和扫描电子显微镜学(SEM)调查。XRD和SEM结果在nanotubularTiO2上显示铂的存在。磅存款的稳定性被周期的voltammetry也在0.5mol/LH2SO4答案调查。当退火了到锐钛矿时,Pt-TiO2/Ti催化剂的electrocatalytic活动在甲醇的电镀物品氧化期间展出改进效果。Pt-TiO2/Tielectrocatalyst上的甲醇氧化的连续周期的voltammograms看唯一的electrocatalytic特征是否与体积磅催化剂上的甲醇氧化相比。当一部electroactive电影的形成发生到工作催化剂表面上时,这因为由自我组织的TiO2nanotubes上的磅粒子的磅(111)方面的吸附的公司的进一步快的氧化。

  • 标签: 二氧化钛纳米管 铂纳米颗粒 循环伏安法 甲醇氧化 电催化反应 退火