简介:Anodesusedfordirectmethanolfuelcells(DMFCs)werefabricatedbymagnetronsputteringprocess.Ahouse-madeplasmasputteringsystemwasusedtodepositPtandPtRuontoun-catalyzedgasdiffusionlayers(GDLs)atdifferentradiofrequency(RF)powersandsputteringgaspressures.ThethinfilmcatalystlayerswerecharacterizedbyX-raydiffraction,energydispersiveX-rayanalysis,andX-rayphotoelectronspectroscopy.Thesputteredanodeswereassembledincustom-mademembraneelectrodeassemblies(MEAs)withacommercialcathodeandtheelectricalperformanceofthesinglecellweretestedunderpassivemethanolsupply,ambienttemperatureandair-breathingconditions.TheelectrochemicalperformanceoftheanodespreparedwithPtRualloywascomparedwithareferenceanodesputteredwithPtonly.X-raydiffractionandX-rayphotoelectronspectroscopyrevealedthatplatinumandrutheniumexistedasaformofalloy.ThecellpolarizationmeasurementsshowedthatallthePtRualloycatalystshadbetterelectrochemicalperformancethanthePt_1catalyst,andthePt_(0.43)Ru_(0.57)catalystachievedthebestperformance.
简介:Inthiswork,ultrasonicirradiationanddestabilizersolventwereusedfordestabilizingcolloidalplatinumdispersions.Thestabilizedplatinumnanoparticleswerepreparedinw/omicroemulsionsystemscomposedofsodiumbis-(2-ethylhexyl)sulfosuccinate(AOT)andfourdifferentsolvents,namely,cyclohexane,n-hexane,n-heptane,andn-nonane.TherecoveryprocessofPtnanoparticlesfromthecolloidalsystemswasperformedbyexposingthecolloidalsamplestoultrasonicirradiationandapplyingvariousdestabilizingsolvents.AnalysisofUV-visiblespectraconfirmsthatthequantityofPtnanoparticlesremovedfromthesuspensiondependsonthelengthoftimeoftheultrasonicirradiationandthenatureofthemicroemulsionoilphase.Acriticaltimefortheultrasonicirradiationhasbeenintroducedforthephaseseparationofcolloidalsystems.Toperformthesolventstudy,fourdestabilizersolvents,namely,dioxane,ethylacetate,diethylether,andtetrahydrofuran,wereusedforbreakingthecolloidalsuspensionofplatinumnanoparticles.Basedonthe’goodsolvent’and’poorsolvent’idea,itisverifiedthattheeffectofthedestabilizersolventsontheaggregationprocessfollowsthefollowingorder:tetrahydrofuran>ethylacetate>dioxane>diethylether.
简介:Platinum-basedanticanceragentsarewidelyusedasfirst-linedrugsincancerchemotherapyforvarioussolidtumors.However,greatsideeffectsandoccurrenceofresistanceremainasthemajordrawbacksforalmostalltheplatinumdrugsdeveloped.Toconquertheseproblems,newstrategiesshouldbeadoptedforplatinumdrugbasedchemotherapy.Modernnanotechnologyhasbeenwidelyemployedinthedeliveryofvarioustherapeuticsanddiagnostic.Itprovidesthepossibilityoftargeteddeliveryofacertainanticancerdrugtothetumorsite,whichcouldminimizetoxicityandoptimizethedrugefficacy.Here,inthisreview,wefocusedontherecentprogressinpolymerbaseddrugdeliverysystemsforplatinum-basedcombinationtherapy.
简介:Thepresentpaperrepresentsthesynthesesofpolypropyloxymethyldithia15-crown-5and18-crown-6supportedonsilicaandtheirplatinumcomplexes.Theplatinumcomplexesareeffectivecatalystsforthehydrosilylationofolefinswithtriethoxysilane.Theinfluencesoftemperature,amountofplatinumcomplexesusedandthenatureofolefinsusedonthecatalyticactivityofthecomplexesarealsoinvestigatedinthispaper.
简介:Silica-boundmercaptoselenaether-containingsilsesquioxaneanditsplat-inumorrhodiumcomplexweresynthesizedfromγ-(2,3-epithiopropyl)propyltrimethoxysi-laneviaring-openingreactionwithbis(2-hydroxyethyl)sclenide,followedbyhydrolysisandimmobilizationonfumedsilica,andthenreactingwithpotassiumchloroplatiniteorrhodiumchlorideinacetoneundernitrogenatmosphere.Itwasfoundthattwonoblemetalcomplexescancatalyzethehydrosilylationofolefinswithtriethoxysilaneeffectively.Theinfluencesoftemperature,theamountofcomplexused,thenatureofolefinoncatalyticactivitywereinvestigated.
简介:IntroductionSelenoetherplatinumcomplexesasanewkindofhydrosilylationcatalysthavebeendrawnmuchatentionrecently.Aseriesofselenoe...
简介:Thechemistryofthethiacrowns,especially,ofthepolymer-supportedthiacrowns,hasnotbeendevelopedtotheextendofthecrownsorazacrowns.Veryfewfunctionalizedthiacrowncompundshavebeenprepared.Nopaperconcerningthepolymer-supportedthiacrownsplatinumcomplexesandtheircatalyticbehaviorhasbeenpublishedyet.Inthispaper,thesynthesisoffumedsilica-supportedpolyundecyloxymethyl-1,4-dithia-7,10,13-trioxacyclopentadecanesiloxaneandsilica-supportedpoly-undecyloxymethyl-1,4-dithia-7,10,13,16-tetraoxacyclooctadecanesiloxane,aswellastheirplatinumcomplexes,andthecatalyticactivityofthecomplexesforthehydrosilylationofolefinswithtriethoxysilanearereported.
简介:Anewtypeofseleniouspolymer,silica-boundpolybispropoxyethyl-selenidesilsesquioxane,anditsplatinumcomplexweresynthesizedfrombis-allyloxyethylselenideviahydrosily-lationwithtriethoxysilane,followedbyimmobilizedonfumedsilica,andthenreactingwithpotassiumchloroplatiniteundernitrogenatmosphereinacetone.Itwasfoundthattheplatinumcomplexcancatalyzethehydrosilylationofolefinswithtriethoxysilaneeffec-tivelyTheeffectsofthenatureofthesubstrate,theamountofcomplexused,andthereactiontemperatureonthecatalyticactivitywereinvestigated.
简介:在自我组织的TiO2nanotubes(Pt-TiO2/Ti)上支持的铂nanoparticles用cathodic减小跟随的电气化学的阳极的氧化被准备。结构和Pt-TiO2/Tielectrocatalyst的化学自然被X光检查衍射(XRD)和扫描电子显微镜学(SEM)调查。XRD和SEM结果在nanotubularTiO2上显示铂的存在。磅存款的稳定性被周期的voltammetry也在0.5mol/LH2SO4答案调查。当退火了到锐钛矿时,Pt-TiO2/Ti催化剂的electrocatalytic活动在甲醇的电镀物品氧化期间展出改进效果。Pt-TiO2/Tielectrocatalyst上的甲醇氧化的连续周期的voltammograms看唯一的electrocatalytic特征是否与体积磅催化剂上的甲醇氧化相比。当一部electroactive电影的形成发生到工作催化剂表面上时,这因为由自我组织的TiO2nanotubes上的磅粒子的磅(111)方面的吸附的公司的进一步快的氧化。