简介:KarstrocksfromtheHuanglongFormationexposedatthemarginoftheEasternSichuanBasincanbedividedintofourtypes:slightlycorroded,moderatelycorrodedporous,intenselycorrodedbrecciatedandintenselycorrodedandreplacedsecondarycalcickarsticrocks.Thecarbon,oxygenandstrontiumisotopecompositionsofthevariouskarstrocksareanalyzedsystematicallyandcomparedtorockswithoutkarstcorrosion.Theresultsindicatethat(1)theHuanglongFormationintheeasternSichuanBasinwasarestrictedbaysuppliedandcontrolledbyfreshwaterinwhichmudmicriteandmud-dolomicriteexhibitlowδ13Candδ18Ovaluesandhigh87Sr/86Srratios;(2)alltypesofkarsticrocksinthepaleokarstreservoirsoftheHuanglongFormationintheresearchareaareaffectedbyatmosphericfreshwaterwiththeδ13Candδ18Ovaluesand87Sr/86Srratiosintheoriginalformationapproachingthoseofatmosphericfreshwater,whichreflectsancienthydrologicalconditions,fluidproperties,isotopicsourceandthefractionationeffect;(3)theintenselycorrodedandreplacedsecondarylimestoneisaffectedbyavarietyofdiageneticfluids,oftenreflectedbyδ13Candδ18Ovalues,whilethe87Sr/86Srratiosexhibitthestrongdegreeofthecorrosion;(4)aftercomparingthe87Sr/86Srratiosofeachtypeofkarstrock,thediageneticfluidsaredeterminedtobemainlyatmosphericfreshwater,anddependingonthestrengthofcorrosion,andthelow87Sr/86Srratiofluidsinthelayerwillparticipateinthekarstprocess.Thecarbon,oxygen,andstrontiumisotopesofdifferentkarsticreservoirscanprovidemeaningfulgeochemicalinformationforforecastingandevaluatingthedevelopmentanddistributionrulesoftheHuanglongFormationatthemarginoftheeasternSichuanBasinintimeandspace.更多还原
简介:15%Ag-addedcubicperovskitesSr0.9La0.1TiO3andRuddlesden-Popper(RP)phasesSr2.7La0.3Ti2O7werefabricatedviahydrothermalsynthesis,coldpressingandhigh-temperaturesintering.Thestructureandthermoelectricpropertieswerealsoinvestigatedforallsamples.TheresultsindicatedthatAgprecipitatedasasecondphase.AgadditionmadeelectricalconductivityandabsoluteSeebeckcoefficientenhanced,asaresult,theZTvalueswereenhancedbothfortwoseries.Comparedwithcubicperovskite,RPphasewassubjectedtosmallerimpactbyAgaddition.ThereasonsforenhancingZTvalueandthedifferentimpactfortwoseriesbyAgadditionwerealsodiscussed.