简介：Thecombinationofboth4,4′-bipyridine(4,4′-bipy)anddihydrogenphosphateanionligandswithcopper(Ⅱ)resultsintheformationofanovellayeredcompoundCu(4,4′-bipy)2(H2PO4)2(H2O)2.ThecrystalstructurecomprisesdiscreteneutralCu(4,4′-bipy)2(H2PO4)2(H2O)2units.Thecopperatom,locatedonthecrystallographictwofoldaxis,iscoordinatedwithtwonitrogenatomsofterminal4,4′-bipyligandsandtwowatermoleculesattheequatorialpositions,andtwodihydrogenphosphateoxygenatomsattheaxialpositions,forminganelongatedoctahedron.Thecomplexisatwo-dimensionaldistortedrhomboidalnetworkpossessingtwokindsofrhomboidswithdimensionsofca.1.6792nm×0.3203nmand1.2778nm×0.3198nm,respectively.Thetwo-dimensionalnetworksarestackedparallellyoneachotheralongc-axistogiveanextendedthree-dimensionalchannelnetworkwithaninterlayerdistanceofca.0.5030nm.Crystaldata:triclinic,spacegroupP-1,a=1.0253(2)nm,b=1.4501(3)nm,c=0.79715(16)nm,α=97.91(3)°,β=90.99(3)°,γ=85.54(3)°,V=1.1703(4)nm3,Z=2,R=0.0892,wR=0.2451.
简介：SrMoO4nanoplatesweresynthesizedbyafacilereversemicroemulsionmethodatroomtemperature.Energyevolutionofthisinsitugrowthprocesswasmonitoredbymeansofamicrocalorimeter.Asharpexothermicpeakfortheinitialreactionandtwodiscontinuousrelativelyweakexothermicpeaksforthesubsequentcrystalgrowthemergedonthemicrocalorimetricheatflowcurve.Basedontheinsituthermokineticdata,therateconstantsofthenucleationprocessandcrystallizationprocessat298.15Kwerecalculatedtobe4.078×10-3and5.033×10-4s-1,respectively.Thegrowthmechanismandenergyevolutionwereinvestigated.
简介：Theacylationof3-pentanoneenaminewasstudiedandanovelformationof4-pyronesfromβ-diketoneenolesterswasfoundinvolvinganintramolecularO-toC-acylshiftfollowedbycyclization.
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简介：Highlyselectivedimerizationofα-methylstyrene(AMS)waseffectedusingaBroenstedacidicionicliquid,[Hmim]^+BF4^-,assolventaswellascatalyst,providingtheindustrialhigh-valueolefin,2,4-diphenyl-4-methyl-1-pentene(1-PT).Thedesireddimer1-PTcouldbeobtainedin90%yieldat96%conversioninthedimerizationofAMSunderoptimizedconditions.Featuresoftheprocedureincludeuseofreadilyavailableionicliquid-catalyst,exclusionofvolatileorganicsolvents,higherselectivityandefficiencyfor1-PT.
简介：采用2步水热法合成了LaPO4∶Eu3＋-Fe3O4复合材料.在LaPO4∶Eu3＋-Fe3O4复合材料中,LaPO4∶Eu3＋为单斜晶相,呈纳米棒状,纳米棒的直径和长度分别为20-100nm和0.2-1μm;Fe3O4为正交晶相、呈20-30nm的颗粒状,Fe3O4粒子紧紧附着在LaPO4∶Eu3＋纳米棒的表面;样品的磁性和发光性质研究表明所合成的LaPO4∶Eu3＋—Fe3O4复合材料既具有发光性质又具有磁性.
简介：Li4Ti5O12（LTO）/carbonnanotubes（CNTs）compositematerialissynthesizedbasedonasolid-statemethodbysand-milling,spray-dryingandcalciningat8508CunderN2flow.TheLTO/CNTssampleswith1wt%and3wt%weightratioofCNTsadditionandthepristineLTOsampleareprepared.TherateperformanceandthethermalstabilityofthesesamplesareinvestigatedbasedonLiMn2O4（LMO）/LTOfull-cell.TheresultsshowthattheweightratioofCNTsadditionhasdistincteffectonLTOperformances.ThecompositematerialsofLTOcompositedCNTshavebetterperformanceathigh-rateduetotheintercalationenhancementbyconductivenetworkofCNTs.Atsecond,theoverchargingtemperatureresponseofthecell’ssurfacewith1wt%CNTsadditionisthelowest.Theparticlesizedistributionismeasuredandthemostuniformparticlesareobtainedwith1wt%CNTsaddition.ThistrendcouldexplainthatthemediumquantityofCNTsisoptimaltoimprovetheheatandmasstransferandpreventtheproblemsofcrystallitegrowinginterferenceandaggregationduringthecalcinationprocess.
简介：Three-dimensional(3D)flowerlikehierarchicalZn2GeO4andMn2+-dopedZn2GeO4microstructureshavebeenpreparedbyafacilehydrothermalapproach.X-Raydiffraction(XRD),fieldemissionscanningelectronmicro-scopy(FESEM),transmissionelectronmicroscopy(TEM)andphotoluminescence(PL)spectrometrywereemployedtocharacterizethesamples.SuchflowerlikehierarchicalZn2GeO4microstructureswithanaveragediameterof3―4μmwerefoundtobeconstructedbyabundantsinglecrystallinenanorodsofabout90nmindiameter.TheluminescentpropertiesofZn2GeO4:xMnphosphorswithdifferentcontentsofMn2+asanactivatorwereinvestigated.TheMn2+-dopedsamplesshowedgreenluminescencecorrespondingtothed-dtransitionofMn2+undertheirradiationofUVlight.Theredshift(from531nmto538nm)inλemwithincreasingMn2+contentwasobservedintheluminescentspectra,whichshouldbeattributedtoaweakcrystalfieldbecauseofthesubstitutionofZn2+byMn2+atadistortedtetrahedrallatticesite.
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简介：Anovelseriesofcalix[4]azacrownderivativeswiththereactionbetweencalix[4]azacrownandthedifferentfluorophorederivatives,whichmaybeusefulfluorescentreceptors,havebeensynthesizedandstructurallycharacterizedbyIR,~1HNMR,~(13)CNMRandMS.Fromtheiranalysisdata,itwasfoundthosecompoundsadoptedaconeconformation.
简介：Anovelquaternarymetalselenide,K_2CdSnSe_4,wassynthesizedviaamolten-saltreactionat550℃.Thecompoundhasaone-dimensionalstructurecontainingachainof_∞~1[CdSnSe_4]~(2-)anionsseparatedbyK~+cations.ThecrystalbelongstothespacegroupI-42m,withtheunitcellparametersa=0.80298(11)nm,b=0.80298(11)nm,c=0.69217(14)nm,α=β=γ=90°.Areflectancespectroscopystudyrevealsthenatureofthesemiconductorwithanenergygapof1.7eVforthecompoundandithasastrongopticalabsorptioninarangeof2—5eV.
简介：ＳＹＮＴＨＥＳＩＳ ＡＮＤ １８３Ｗ ＮＭＲ ＣＨＡＲＡＣＴＥＲＩＺＡＴＩＯＮ ＯＦ Ｐ４Ｗ３０Ａｌ４（Ｈ２Ｏ）２Ｏ１１２２０－ ＨＥＴＥＲＯＰＯＬＹＡＮＩＯＮＳＹＮＴＨＥＳＩＳＡＮＤ１８３ＷＮＭＲＣＨＡＲＡＣＴＥＲＩＺ?..
简介：Afacilesyntheticroutetotwoseco-eudesmane,4,5-dioxo-10-epi-4,5-seco-γeudesmane(1)and4,5-dioxo-10-epi-4,5-seco-γ-eudesmol(2)from(+)-dihydrocarvonehasbeendescribed.Avoidingexpensivereagents,thishighlyeconomicmethodespeciallysuitsforthesynthesisof4,5-seco-eudesman-typeandophianon-typesesquiterpeneswithadoublebondatposition11and12.
简介：Anovelclassoffulgimide,(Z)-4-oxazolylfulgimide((Z)-1-benzyl-4-isopropylidene-3-[1-(2-aryl-5-methyloxazolyl)ethylidene]tetrahydropyrrole-2,5-dione),wassynthesizedbythereactionof(Z)-4-oxazolylfulgide(4-isopropylidene-3-[1-(2-aryl-5-methyloxazolyl)ethylidene]tetrahydrofuran-2,5-dione)withbenzylamine.Photochromicpropertyof(Z)-4-oxazolylfulgimidewasstudied.Comparedwith(Z)-4-oxazolylfulgide,theabsorptionmaximumofthecoloredformof(Z)-4-oxazolylfulgimideisbathochromic-shifted.Substituentsonthearylringaffecttheabsorptionmaximumoftheopenformandthecoloredformof(Z)-4-oxazolylfulgimide.
简介：Thenon-isothermaldecompositionoflead2,4,6-trinitroresorcinatemonohydrate,Pb(TNR)·H2O,wasinvestigatedbymeansofTG-DTA,DSCandIR.Thethermaldecompositionmechanismandthedissociatedkineticswerealsoinvestigated.ThekineticparameterswereobtainedfromtheanalysisoftheDSCcurvesbyintegralanddifferentialmethods.ThemostprobablekineticmodelfunctionofthedehydrationreactionofPb(TNR)·H2Owassuggestedbythecomparisonofthekineticparameters.
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