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60 个结果
  • 简介:Bimetalliccobalt-rutheniumnanocatalystssupportedoncarbonnanotubes(CNTs)arepreparedusingmicroemultiontechniquewithwater-to-surfactantratiosof0.5—1.5.ThenanocatalystswereextensivelycharacterizedbydifferentmethodsandtheiractivityandselectivityinFischer-Tropschsynthesis(FTS)havebeenassessedinafixed-bedmicroreactor.Thephysicochemicalpropertiesandperformanceofthenanocatalystswerecomparedwiththecatalystpreparedbyimpregnationmethod.Verynarrowparticlesizedistributionhasbeenproducedbythemicroemulsiontechniqueatrelativelyhighloadingsofactivemetals(15wt%Coand1wt%Ru).AccordingtoTEMimages,smallCoparticles(2—7nm)weremostlyconfinedinsidetheCNTs.Comparingwiththecatalystpreparedbyimpregnation,theuseofmicroemulsiontechniquewithwatertosurfactantratioof0.5decreasedtheaveragecobaltoxideparticlesizeto4.8nm,thedispersionwasalmostdoubledandthereductionincreasedby28%.Activityandselectivitywerefoundtobedependentonthecatalystpreparationmethodandwater-to-surfactantratio(aswellascobaltparticlesizes).COconversionincreasedfrom59.1%to75.1%andtheFTSrateincreasedfrom0.291to0.372gHC/(gcath).C5+liquidhydrocarbonsselectivitydecreasedfrom92.4%to87.6%.

  • 标签: FISCHER-TROPSCH synthesis COBALT RUTHENIUM MICROEMULSION particle
  • 简介:AbstractObjective:Mifepristone (RU486), one of the most common medications for artificial abortion, attenuates the immunoregulatory effects of progesterone. However, the specific immune regulatory mechanism of RU486 in abortion remains unknown. We intended to investigate the immunomodulatory effects of RU486 on abortion.Methods:Sixty female mice were divided into the control group (0 mg RU486) and RU486 group (2 mg/kg RU486). The uterus, peripheral blood, and spleen were obtained for isolation of specific cell types. The population and phenotype of immune cells in the decidua, peripheral blood, and spleen were analyzed using flow cytometry. Statistical differences between groups were determined using two-tailed t-test. For all statistical tests, P < 0.05 was considered statistically significant.Results:RU486 effectively induced abortion in pregnant mice, with a significantly higher number of decidual macrophages (dMφ) (control group = 25.55% ± 2.467%, RU486 group = 19.41% ± 1.423%; P < 0.05), especially the major histocompatibility complex IIhigh subset. No difference in Mφ number was observed in the spleen or peripheral blood. Moreover, the dMφ from mice with RU486-induced abortion displayed a remarkable activated phenotype, with increased expressions of inducible nitric oxide synthase, tumor necrosis factor-α, and interleukin (IL)-12 but decreased expressions of arginase-1 and IL-10. We also found elevated levels of decidual CD4+ T-cells in the RU486 group that exhibited a higher level of the proinflammatory cytokine interferon-γ and a lower level of the anti-inflammatory cytokines, IL-4 and IL-10.Conclusions:We report a new mechanism of RU486-induced abortion via the regulation of innate cell Mφ activation and the adaptive response of CD4+ T-cells present in the decidua but not the periphery.

  • 标签: Decidual CD4+ T-Cells Decidual Macrophages Induced Abortion RU486
  • 简介:Emissionquenchingof[Ru(bpy)2(4,4’-dcbpy)](PF6)2(1)bybenzenamine,4-[2-[5-[4-[4-dimethylamino]phenyl]-4,5-di-hydro-1-phenyl-1H-pyrazol-3-yl]-ethenyl]-N,N-dimetyl(2)or1,5-diphenyl-3-(2-phenothiazine)-2-pyrazoline(3)wasobserved.Measurementsoftheemissiondecayof1beforeandafteradditionof2or3bysinglephotoncountingtechniquecon-finnedtheobservations.Theemissionquenchingof1by2or3wassubmittedtoStern-Volmerequation.Itwascalculatedthatthequenchingrateconstants(kq)are5.5×109(mol/L)-1s-1for2and4.0×109(mol/L)-1s-1for3,respectively.Theseresultsindicatedacharacterofdynamicquenchingprocess.Thesinglet-stateof2or3wasalsoquenchedby1.ThequenchingbehaviorsdidnotconformtotheStern-Volmerequationandinvolvedbothstaticanddynamicquenchingprocesses.Theapparentquenchingrateconstant(kapp)wascalculatedtobe3×109(mol/L)-1fortheinteractionofexcited2with1,and1.2×109(mol/L)-1forthatofexcited3wit

  • 标签: RUTHENIUM COMPLEXES PYRAZOLINE compounds electrontransfer dynamic
  • 简介:大约半年前,惠普推出了一款型号为HPCompaq2133的迷你笔记本电脑,它出色的外观设计为人所称道,但由于硬件原因,性能偏弱和发热量大的问题是一直无法解决的顽疾。此次,HPmini1010TU携英特尔凌动(Atom)处理器登场,以一袭黑衣示人,带来了不同的感觉。

  • 标签: 惠普 迷你笔记本电脑 上网 魔法 COMPAQ 外观设计
  • 简介:摘要目的探讨1010例妇科门诊患者阴道分泌物检查结果分析。方法回顾性分析2017年1月~2017年12月我院妇科1010例门诊患者的阴道分泌物检查结果。结果在妇科门诊患者阴道分泌物检查的1010例患者中,阴道清洁度Ⅰ度患者有9例,检出率为0.79%;阴道清洁度Ⅱ度患者有33例,检出率为2.77%;阴道清洁度Ⅲ度患者有165例,检出率为14.65%;阴道清洁度Ⅳ度患者有803例,检出率为21.39%。组间比较差异有统计学意义(P<0.05)。结论阴道分泌物检查可作为门诊妇科常规诊疗手段的首选方法,能及时发现妇女的身体情况,在临床初筛妇科感染性疾病、临床用药指导方面具有较高的临床价值。

  • 标签: 妇科门诊 阴道分泌物 常规检查 阴道炎
  • 简介:摘要:为切实提高煤炭开采质量,做好煤炭资源的优化调配,对采空区问题进行有效的解决,全面提升煤炭开采与利用效率。本文将以1010机巷为例,对沿空安全掘进技术及运用进行分析与研讨,本文首先对1010机巷进行简单综述,其次对沿空安全掘进施工进行简析,最后对沿空安全掘进技术的运用进行分析,以供参考与借鉴。

  • 标签: 沿空安全掘进 1010机巷 运用
  • 简介:(CO+Cs)/Ru(101^-0)共吸附的体系中,CO分子由于受Cs原子强烈影响,分子轨道发生重新杂化组合。CO分子原来在清洁Ru(101^-0)表面上结合能位于7.5eV处相重叠的5σ和1π轨道对应谱峰分裂为两峰,结合能分别位于6.3和7.8eV处,其中6.3eV处的谱峰来自CO分子1π轨道的一支,它显示出该分子轨道沿衬底<0001>晶向的镜面反对称性。CO分子1π轨道的另一支和5σ轨道在结合能7.8eV处相重叠。

  • 标签: 同步辐射 CO Cs/Ru(101^-0)表面 共吸附 铯/钌 一氧化碳
  • 简介:Synthesis,structureandmagneticpropertiesofRudopedperovskitestructuredmanganiteLa0.5Sr0.5MnO3wereinvestigatedexperimentally.Ahydrothermalmethodwasusedforthepreparationofthesamples.Ahigh-temperatureannealingprocesswasalsoemployedtomakeacomparison.AslightlyenhancementoftheunitcellvolumewasobservedwiththeincreaseofRuconcentration.Scanningelectronmicroscopyshowsthatthematerialsaremadeupofcube-shapedparticleswithdimensionofseveralmicrometers.Importantly,itisfoundthatboththeCurietemperatureTCandsaturationmomentcanbereducedbyRudoping.ThevalueofcoercivefieldisnotaffectedbytheintroductionofRu.

  • 标签: La0.5Sr0.5MnO3 HYDROTHERMAL synthesis RU DOPING CURIE
  • 简介:我厂1996年从上海爱斯特电子有限公司购买一台DM1010型钙铁煤分析仪(以下简称分析仪),使用至今已有6年,由于校验及时和保养得当,从未出现生料数据偏差大的现象。该分析仪具有分析速度快、准确度高、人为误差小、劳动强度低、无污染等特点。不仅提高了生料质量,而且烧成容易,节能效果明显。

  • 标签: 钙铁煤分析仪 仪器校验 DM1010型 滑板机
  • 简介:近日,微博诞生了一对动人的“微爱情”——一名微博网友透过微博向自己的心上人求婚,在网友们的鼎力支持下,他成功了。

  • 标签: 网友 成功 求婚 恋人 祝福 爱情
  • 简介:Aseriesof3wt%Ruembeddedonorderedmesoporouscarbon(OMC)catalystswithdifferentporesizeswerepreparedbyautoreductionbetweenrutheniumprecursorsandcarbonsourcesat1123K.RunanoparticleswereembeddedonthecarbonwallsofOMC.CharacterizationtechnologiesincludingpowerX-raydiffraction(XRD),nitrogenadsorption-desorption,transmissionelectronmicroscopy(TEM),andhydrogentemperature-programmedreduction(H2-TPR)wereusedtoscrutinizethecatalysts.ThecatalystactivityforFischer-Tropschsynthesis(FTS)wasmeasuredinafixedbedreactor.Itwasrevealedthat3wt%Ru-OMCcatalystsexhibitedhighlyorderedmesoporousstructureandlargesurfacearea.Comparedwiththecatalystswithsmallerpores,thecatalystswithlargerporeswereinclinedtoformlargerRuparticles.These3wt%Ru-OMCcatalystswithdifferentporesizesweremorestablethan3wt%Ru/ACcatalystduringtheFTSreactionsbecauseRuparticleswereembeddedonthecarbonwalls,suppressingparticlesaggregation,movementandoxidation.ThecatalyticactivityandC5+selectivitywerefoundtoincreasewiththeincreasingporesize,however,CH4selectivityshowedtheoppositetrend.ThesechangesmaybeexplainedintermsofthespecialenvironmentoftheactiveRusitesandthediffusionofproductsintheporesofthecatalysts,suggestingthattheactivityandhydrocarbonselectivityaremoredependentontheporesizeofOMCthanontheRuparticlesize.

  • 标签: 碳纳米粒子 合成孔径 有序介孔 嵌入式 催化性能 固定床反应器
  • 简介:应用量子化学DVXα方法对钌系氰氯络合物进行了系统的理论计算和解析,确定了相应的稳定几何形态和微观电子结构,为合成、应用和深入研究它们的性能提供了重要的理论依据.

  • 标签: 钌系氰氯络合物 电子结构 DVXα方法
  • 简介:极其细小磨擦非结晶的合金催化剂被化学减小与KBH4准备。在在气压的cinnamaldehyde的液体阶段加氢期间,Ru-B催化剂准备了展出优秀选择到cinnamyl酒精。当加氢与超声的照耀被执行时,当到cinnamyl酒精的选择仍然保持几乎未改变时,反应率能极大地被提高。加氢率随超声的频率或照耀时间的增加被增加。根据各种各样的描述,例如XRD,XPS,TEM,赌注和ICP,结构、电子的特征上的超声的照耀的效果磨擦催化剂简短被学习。同时,催化表演上的ultrasonication的提升效果也基于cinnamaldehyde的选择加氢被讨论到cinnamyl酒精。

  • 标签: 钌-硼无定形合金 催化剂 超声照射 肉桂醛 肉桂醇 催化加氢
  • 简介:Twomajorbacterialblight(BB)resistancegenes(Xa21andxa13)andamajorgeneforblastresistance(Pi54)wereintrogressedintoanIndianricevarietyMTU1010throughmarker-assistedbackcrossbreeding.ImprovedSambaMahsuri(possessingXa21andxa13)andNLR145(possessingPi54)wereusedasdonorparents.Marker-assistedbackcrossingwascontinuedtillBC2generationwhereinPCRbasedfunctionalmarkersspecificfortheresistancegeneswereusedforforegroundselectionandasetofparentalpolymorphicmicrosatellitemarkerswereusedforbackgroundselectionateachstageofbackcrossing.SelectedBC2F1plantsfrombothcrosses,havingthehighestrecoveriesofMTU1010genome(90%and92%,respectively),wereintercrossedtoobtainintercrossF1(ICF1)plants,whichwerethenselfedtogenerate880ICF2plantspossessingdifferentcombinationsoftheBBandblastresistancegenes.AmongtheICF2plants,seventriplehomozygousplants(xa13xa13Xa21Xa21Pi54Pi54)withrecurrentparentgenomerecoveryrangingfrom82%to92%wereidentified.AllthesevenICF2plantsshowedhighresistanceagainstthebacterialblightdiseasewithalesionlengthsofonly0.53–2.28cm,1%–5%diseaseleafareasanddiseasescoringvaluesof‘1'or‘3'.ThesevenICF2plantswereselfedtogenerateICF3,whichwerethenscreenedforblastresistance,andallwereobservedtobehighlyresistanttothediseases.SeveralICF3linespossessinghighlevelofresistanceagainstBBandblast,coupledwithyield,grainqualityandplanttypeonparwithMTU1010wereidentifiedandadvancedforfurtherselectionandevaluation.

  • 标签: 水稻科学 农业
  • 简介:抗氧剂1010是最重要的抗氧剂品种。本文对国外大型生产装置和国内小型生产装置的生产工艺进行了简要的介绍,并阐述了国内外在抗氧剂1010生产工艺技术领域的研发工作动态。

  • 标签: 抗氧剂1010 生产工艺 工艺流程 研究开发工作
  • 简介:摘要:采用极性色谱柱,高效液相色谱建立了一种复配助剂组分含量的分析方法,此复配助剂中主要含有抗氧剂1010、330和168。抗氧剂的浓度与峰面积有良好的线性关系,该方法有着快速、准确、灵敏度高及稳定性好等优点,可以表征聚乙烯mPE3010复配添加剂中抗氧剂1010、330和168的含量,可用于聚乙烯mPE3010复配添加剂质量的控制。

  • 标签: 高效液相色谱 抗氧剂 复配添加剂 
  • 简介:随着生物柴油的产量急剧增加,其副产物甘油的利用成为国内外研究的焦点。本实验考察了不同Ru金属的负载量对Ru-Ir-ReOx/SiO2催化甘油原位产氬制1,2-丙二醇的影响。在Ru负载量为0.5wt%时,反应时间为61h,反应温度为190℃,甘油转化率可达37%。增加催化剂的量后,甘油的转化率提升至54%,1,2-丙二醇和丙酮醇的选择性分别为34.5%和30.7%。

  • 标签: 甘油 1 2-丙二醇 Ru-Ir-ReOx/SiO2催化剂