简介:Fouriertransformedinfraredspectrometry(FTIR)and27AlMagicAnglespinning(MAS)nuclearmagneticresonancespectroscopywereemployedtocharacterizearsenateadsorptiononamorphousAlgelswithKegginstructureatpH=4–10.Thesestudieshaveproventhat:thesurfacecomplexspeciesofarsenateshowsignificantdifferencesunderacidicandalkalineconditions,whichwasdeducedbasedontheAs-Ostretchingvibrationbandslocatedrespectivelyat774and870cm-1;poorlycrystallineAl13(orAl)-arsenateprecipitationcouldbeeasilyformedunderacidmediumconditionandhighloadinglevel,whichwassupportedbycomparingtheAs-Ovibration(at≈732cm-1)ofprecipitationtoadsorbedAlgels;arsenate(AsO43-)adsorptionhasnoeffectontheKegginstructureofAlgelswithbasicity(R)=2.6and3.0,evenathighloadinglevel,asevidencedbythesignalat≈63×10-6ofmagicanglespinning(MAS)-27AlNMR.Theadsorptionenvelopewasdeterminedbyconventionalbatchexperiments.
简介:摘要:对一种10mm厚Al-4.3Zn-1.3Mg合金板材进行时效处理并研究了不同时效制度对板材力学性能和组织的影响规律。结果表明,当采用120℃/28h的工艺制度进行时效处理时,板材获得了最佳的强度性能。
简介:摘要:对一种10mm厚Al-4.3Zn-1.3Mg合金板材进行时效处理并研究了不同时效制度对板材力学性能和组织的影响规律。结果表明,当采用120℃/28h的工艺制度进行时效处理时,板材获得了最佳的强度性能。
简介:Thevolcano-sedimentarysuccessionaroundWadiZaghrainSinai,atthenorthernmostsegmentoftheArabianNubianShield,comprisesvolcanicrocksinterbeddedwithratherimmaturesediments.Thesuccessionisdominatedbyintermediatetosilicicvolcanicsofmedium-tohigh-Kcalc-alkalineaffinity.Itisdividedintotwounits,thelowerunitincludesintermediaterocksanddacitesinterbeddedwithgraywackes,semi-pelitesandpelitesandtoppedbypolymictconglomerates.Thisunitissubjectedtofoldingandregionalmetamorphism(uptogarnetzone)andisintrudedbyquartzdiorite-granodioriteinducing,locally,low-pressurecontactthermalmetamorphism.Theunmetamorphosedupperunitencompassesacidvolcanicsintercalatedwithlitharenite,sublithareniteandminorarenite.Therhyolitesofthisunitpertaintothehighlyfractionatedgranitesandarecharacterizedbyanagpaiticindex(NK/A)rangingfrom0.87to0.96.Theymayreflecteitherextensiveinteractionofsubduction-relatedmagmaswiththecontinentalcrustorachangeinthetectonicregime.Thepresentlithologicalandgeochemicalcharacteristicsofthestudiedsedimentstogetherwithavailablezirconagesindicateratherdistalprovenanceoftheirdetritus.Thisdetrituscomprisesfluvial-alluvialsedimentsaccumulatedintheintermontanebasins,whicharehalf-grabensortiltedfaultblocks.Thetectonicsettingofthedepositionalbasinsisactivecontinentalmarginandcontinentalislandarcs.GeochemicalpatternsoftheZaghravolcano-sedimentarysuccessionindicatetheircorrelationwiththeDokhanVolcanics-HammamatClasticssequenceoftheEasternDesertofEgypt.Also,theZaghravolcanicsdisplaygeochemicalsimilaritieswiththoseexposedinSinai,attheRutig,FeraniandIqnaShar’aareas.TheZaghrasuccessionisdatedasEdiacaranbutisnotrelatedeithertotheensimaticislandarcassemblageortotherift-relatedassemblageformedduringtheearlystagesofthebreak-upofRodiniaaspreviouslythought.