High-frequency dielectric properties of BSTO ceramic prepared with hydrothermal synthesized SrTiO3 and BaTiO3 powders

(整期优先)网络出版时间:2009-05-15
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BSTOdielectricceramicwaspreparedfromSrTiO3andBaTiO3powderssynthesizedbyhydrothermalmethod,aswellasfromBa0.6Sr0.4TiO3powdersynthesizedbyconventionalsolid-statereaction.Theformercanbesinteredatarelativelylowtemperatureof1120℃.CharacterizationbySEMshowedthatthegrainshapesofbothceramicsarecubical,thoughthegrainsizeoftheformerismuchsmaller.Dielectricconstantsmeasuredat20℃wereshowntovarywithfrequencyintherangefrom1kHzto2MHzanddcbiasfield,andfurtherthatthedielectriclossoftheformertobelessthan2×10-3inthefrequencyrangeof20kHzto1MHz,muchsmallerthanthatofthelattersample.Fortheformer,temperaturedependenceofdielectricconstantismuchflatterandthereexistsanextendedphasetransitiondiffusioncoveringawidetemperaturerangeofCurietemperatureTc.Thesmallergrainsizeoftheformerdepressesthedcbiaselectricalfielddependenceofdielectricconstant.Thetunabilityis7%underabiasfieldof0.6kV/mmdc.