简介:Directconversionoffructose-basedcarbohydratesto5-ethoxymethylfurfural(EMF)catalyzedbyLewisacidinethanolwasinvestigated.ItwasfoundthatBF3(Et)2Owasfavorablefor5-hydroxymethylfurfural(HMF)etherificationtoEMF.BF3(Et)2OcombinationwithAlCl36H2Owiththemolarratioof1wasaneffectivecatalystsystemforsynthesisofEMFfromfructose-basedcarbohydrates.55.0%,45.4%and23.9%ofEMFyieldswereobtainedfromfructose,inulinandsucroseunderoptimizedconditions,respectively.
简介:WepresentthetemperaturedependentelectricaltransportmeasurementsofAg/Si(111)-(√3×√3)R30°bytheinsitumicro-four-pointprobemethodintegratedwithscanningtunnelingmicroscopy.Thesurfacestructurecharacterizationsshowhexagonalpatternsatroomtemperature,whichsupportstheinequivalenttriangle(IET)model.Ametal-insulatortransitionoccursat-115K.Thelowtemperaturetransportmeasurementsclearlyrevealthestronglocalizationcharacteristicsoftheinsulatingphase.
简介:Basedonthethermodynamictheory,anorthotropicdamageconstitutivemodelwasdevelopedtodescribethenonlinearmechanicalbehaviorofC/SiCcomposites.Thediferentnonlinearkinematicandisotropichardeningfunctionswereadoptedtodescribeaccuratelythedamageevolutionprocesses.Thedamagevariablesweredefinedwiththedamagedmodulusandtheinitialundamagedmodulusonenergyequivalenceprinciple.Theinitialorthotropyanddamagecouplingwerepresentedinthedamageyieldfunction.Tensileandin-planeshearloadingandunloadingtestswereperformed,andagoodagreementbetweenthemodelandtheexperimentalresultswasachieved.
简介:LetXbeaweaklyCauchynormedspaceinwhichtheparallelogramlawholds,CbeaboundedclosedconvexsubsetofXwithonecontractingpointandTbean{a,b,c}-generalized-nonexpansivemappingfromCintoC.Weprovethattheinfimumoftheset{||x-T(x)||}onCiszero,studysomefactsconcerningthe{a,b,c}-generalized-nonexpansivemappingandprovethattheasymptoticcenterofanyboundedsequencewithrespecttoCissingleton.Dependingonthefactthatthe{a,b,0}-generalized-nonexpansivemappingfromCintoChasfixedpoints,accordingly,anotherversionoftheBrowder’sstrongconvergencetheoremformappingsisgiven.
简介:在α次积分C半群和双连续n次积分C半群的基础上,探讨了双连续α次积分C半群的扰动性,得到了双连续α次积分C半群的扰动定理,并且在局部Lipschitz连续条件下证明双连续α次积分C半群的扰动理论仍然成立.
简介:TiO2@ZrO2@Y2O3:有coremultishell结构的Eu3+合成粒子通过layer-by-layer(LBL)的联合被综合自己组装方法和一个solgel过程。获得的样品与扫描电子被描绘显微镜学(SEM),传播电子显微镜学(TEM),X光检查光电子光谱学(XPS),X光检查衍射(XRD),和荧光spectrophotometry。结果证明合成粒子有coremultishell结构,球形的形态学,和狭窄的尺寸分布。TiO2核心上的ZrO2层的存在能有效地阻止在TiO2核心和Y2O3壳之间的反应;为在在TiO2@ZrO2@Y2O3的TiO2核心和Y2O3壳之间的反应的温度:Eucoremultishell黄磷能被300提高
简介:ThecorrelationbetweenphasestructuresandsurfaceacidityofAl2O3supportscalcinedatdifferenttemperaturesandthecatalyticperformanceofNi/Al2O3catalystsintheproductionofsyntheticnaturalgas(SNG)viaCOmethanationwassystematicallyinvestigated.Aseriesof10wt%NiO/Al2O3catalystswerepreparedbytheconventionalimpregnationmethod,andthephasestructuresandsurfaceacidityofAl2O3supportswereadjustedbycalciningthecommercialγ-Al2O3atdifferenttemperatures(600–1200C).COmethanationreactionwascarriedoutinthetemperaturerangeof300–600Catdifferentweighthourlyspacevelocities(WHSV=30000and120000mL·g-1h-1)andpressures(0.1and3.0MPa).ItwasfoundthathighcalcinationtemperaturenotonlyledtothegrowthinNiparticlesize,butalsoweakenedtheinteractionbetweenNinanoparticlesandAl2O3supportsduetotherapiddecreaseofthespecificsurfaceareaandacidityofAl2O3supports.Interestingly,NicatalystssupportedonAl2O3calcinedat1200C(Ni/Al2O3-1200)exhibitedthebestcatalyticactivityforCOmethanationunderdifferentreactionconditions.LifetimereactiontestsalsoindicatedthatNi/Al2O3-1200wasthemostactiveandstablecatalystcomparedwiththeotherthreecatalysts,whosesupportswerecalcinedatlowertemperatures(600,800and1000C).ThesefindingswouldthereforebehelpfultodevelopNi/Al2O3methanationcatalystforSNGproduction.