简介:研究了不同烧结温度对纳米WC-6Co复合粉烧结的影响.采用CSS-44100型万能材料实验机进行抗弯强度测试.材料的硬度通过HR-150A型洛氏硬度仪测量.分别在S-3400N型扫描电镜的背散射电子和二次电子模式下观察试样的显微组织形貌和断口形貌.结果表明:当烧结温度在1460℃时,晶粒分布均匀,材料的孔隙率最低.随烧结温度的升高,材料的抗弯强度和硬度先增加后降低.当在1460℃烧结时,较低的孔隙率和显微组织分布均匀导致材料有较高的抗弯强度.随烧结温度的继续增加,晶粒聚集长大现象严重,孔隙率增加,导致材料的抗弯强度大幅降低.当烧结温度在1460℃时,材料有较高的硬度和断裂韧性.
简介:采用本研究组原创的原位合成短流程专利技术,结合制备方案和工艺参数优化,研制出了具有高度WC特征晶面取向分布的WC-Co硬质合金块体材料。利用X射线衍射分析和背散射电子衍射(EBSD)方法对所制备的硬质合金材料的物相组成、取向特征进行了系统的表征研究,同时对WC特征晶面取向分布形成机理从粉末物相组成和烧结过程参数两个方面进行了分析讨论。研究结果表明:WC晶粒呈现明显的板状晶,硬质合金块体在垂直于烧结压力方向上具有WC晶粒基面(0001)择优取向分布,在平行于烧结压力方向上,基面面积分布比例明显减少,相应的出现了WC晶粒柱面(10-10)的择优取向分布。粉末中缺碳相含量和烧结过程中辅助压力的大小对最终制备的合金块体WC晶粒的取向分布起着决定性的作用,缺碳相在烧结的过程中进一步碳化形成板状WC晶粒并在压力的作用下趋于基面垂直于压力方向分布为块体中WC特征晶面取向分布的主要形成机制。
简介:Dopantsanddefectsareimportantinsemiconductorandmagneticdevices.Strategiesforcontrollingdopinganddefectshavebeenthefocusofsemiconductorphysicsresearchduringthepastdecadesandremaincriticaleventoday.Co-dopingisapromisingstrategythatcanbeusedforeffectivelytuningthedopantpopulations,electronicproperties,andmagneticproperties.Itcanenhancethesolubilityofdopantsandimprovethestabilityofdesireddefects.Duringthepast20years,significantexperimentalandtheoreticaleffortshavebeendevotedtostudyingthecharacteristicsofco-doping.Inthisarticle,wefirstreviewthehistoricaldevelopmentofco-doping.Then,wereviewavarietyofresearchperformedonco-doping,basedonthecompensatingnatureofco-dopants.Finally,wereviewtheeffectsofcontaminationandsurfactantsthatcanexplainthegeneralmechanismsofco-doping.
简介:采用金属粉型药芯焊丝自保护明弧焊制备Cr9Mn6Nb2WVSiTi奥氏体耐磨堆焊合金,借助XRD,SEM,EDS及光学显微镜研究外加WC颗粒对其显微组织及耐磨性的影响。结果表明,随焊丝药芯中WC增加,奥氏体晶粒细化,沿晶分布的多元合金化碳化物数量增加。初生γ-Fe相原位析出了(Nb,Ti,V)C相和残留WCx颗粒,起到晶内弥散强化作用,沿晶分布的(Nb,Ti,V)C和M6C(M=Fe,Cr,Mn,V,W)相隔断了网状或树枝状的沿晶M7C3相,使其细化、断续分布而提高合金韧性,减轻沿晶碳化物数量增加的不利影响。硬度和磨损测试结果显示,明弧堆焊奥氏体合金洛氏硬度仅为40~47,但其磨损质量损失低于高铬铸铁合金,具有良好耐磨性;随外加WC含量提高,奥氏体合金晶内和晶界显微硬度差异显著减小,合金表面趋于均匀磨损而改善耐磨性。该奥氏体合金的磨损机制主要是磨粒显微切削,适用于带有一定冲击载荷磨粒磨损的工况下使用。
简介:OnApril1,CAFIUworkedtogetherwiththeFriedrichEbertStiftung(FES)BeijingOfficeinhostingaRoundtablemeetingon"EnergyTransitionandSustainableEconomicPolicy".InvitedtoattendtheroundtablemeetingwereProf.Franz-JosefBr(u|¨)ggemeier,renownedGermansociologistandeconomist,Prof.LiHengyuan,formerDirector-Generalof
简介:Low-CoLa1.8Ti0.2MgNi8.9Co0.1alloyswerepreparedbymagneticlevitationmeltingfollowedbyannealingtreatment.TheeffectofannealingonthehydrogenstoragepropertiesofthealloyswasinvestigatedsystematicallybyX-raydiffraction(XRD),pressure-compositionisotherm(PCI),andelectrochemicalmeasurements.TheresultsshowthatallsamplescontainLaNi5andLaMg2Ni9phases.LaCo5phaseappearsat1,000℃.Theenthalpychangeofallhydridesiscloseto-30.6kJ·mol-1H2ofLaNi5compound.Annealingnotonlyincreaseshydrogencapacityandimprovescyclingstabilitybutalsodecreasesplateaupressureat800and900℃.Afterannealing,thecontractionofcellvolumeandtheincreaseofhydridestabilitycausethehighratedischargeabilitytoreduceslightly.Theoptimumalloyisfoundtobeoneannealedat900℃,withitshydrogencapacityreachingupto1.53wt%,anddischargecapacityremaining225.1mAh·g-1after140charge–dischargecycles.
简介:Therectificationratiooforganicmagneticco-oligomerdiodesisinvestigatedtheoreticallybychangingthemolecularlength.Theresultsrevealtwodistinctlengthdependencesoftherectificationratio:forashortmoleculardiode,thechargecurrentrectificationchangeslittlewiththeincreaseofmolecularlength,whilethespin-currentrectificationisweakenedsharplybythelength;foralongmoleculardiode,boththecharge-currentandspin-currentrectificationratiosincreasequicklywiththelength.Thetwokindsofdependenceswitchataspecificlengthaccompaniedwithaninversionoftherectifyingdirection.Themolecularortibalsandspin-resolvedtransmissionanalysisindicatethatthedominantmechanismofrectificationsuffersachangeatthisspecificlength,thatis,fromasymmetricshiftofmoleculareigenlevelstoasymmetricspatiallocalizationofwavefunctionsuponthereversalofbias.Thisworkdemonstratesafeasiblewaytocontroltherectificationinorganicco-oligomerspindiodesbyadjustingthemolecularlength.更多还原
简介:LakesinTibetPlateauwithlittleeffectsofhumanactivitiesserveasimportantindicatorsofclimatechange.ThisstudyanalysedremotesensingdataandlongtermclimatevariablestoexaminethehydrologicalresponseoflakesinNamCoBasin.TheareachangesoflakeswereextractedbyLandsatTM/ETM+andanalysedbySRTM3DEM.AndtheICESatelevationdatabetween2003and2009wereusedtoobservethelakeleveloftheNamCoLake.Theresultsshowthatthenumberofnewformedglacierlakesincreasedby36%andtheareaofglacierlakesincreasedby36.7%(0.97km~2)from1991to2011.Atthesametime,thesurfaceareaoftheNamCoLakeexpandedby3.71%(72.64km~2)oftheoriginalsizein1991,withatendencyvalueof3.63km~2peryear.ThelakeleveloftheNamCoLakeshowsanincreasetendencyof0.24mperyearduring2003–2009.Thesevariationsappeartoberelatedtoanincreaseinmeanannualtemperatureof0.06oCperyear,andanincreaseinannualprecipitationof2.1mmperyearinsummerinthelasttwodecades.Theincreasednumberoflakesandincreasedareaofglaciallakesreachedapeakatanaltitudeof5500–5600ma.s.l..Thenumberofnewformedglacierlakesandtheareaofglacierlakestendtohigheraltitudes.ClimatechangehasanimportantimpactonthevariationoftheglacierlakesandtheNamCoLake.
简介:磁性的元素Fe,公司和Ni的线性热扩大(CLE)的系数用与MATLAB计算相结合的理论模型从试验性的信息被估计。模型参数能精确地被决定,并且估计的数据在对试验性的结果的好同意。便于评价,热扩大的理论被使用把CLE分开成它的无磁性、磁性的部件。对CLE的无磁性的贡献的计算基于MnBi/NdFeB混血儿的修改Grc性质结合的磁铁都逐渐地减少,当混合磁铁的密度几乎线性地改善时。在293-398的一个温度范围?K,混合磁铁的coercivity温度系数从0.59逐渐地改善?%比较。建模和频率与二低角落频率认为压力消除阀门是一个秒顺序系统是合理的试验性的结果表演。PID控制,死了的乐队赔偿控制和鷸?鷸??
简介:OnApril6-7,2016,the'China-EUThinkTankDialogue:ALong-TermVisionof2020Agendaand4Partnerships'washeldatDiaoyutaiStateGuesthouseinBeijing.Thedialogue,supportedbytheChineseMinistryofForeignAffairsandtheDelegationoftheEuropeanUniontoChina,wasco-hostedbyChinaInstituteofInternationalStudies(CIIS)andEU-ChinaPolicyDialogueSupportFacility(PDSF).PresidentofCIISAmbassadorSuGepresidedovertheopeningceremony.ChineseAssistantForeign
简介:Tris-(8-hydroxyquinoline)-aluminumeAlq3T–basedorganiclight-emittingdiodeswithCoelectrodearefabricated.Thepositivemagneticelectroluminescence(MEL)andmagneticconductance(MC)areobservedinthesamples,reaching4.35%and1.67%underthefieldof42mTat50K,respectively,andtheMELandMCtracescanbefittedtonon-Lorentzianlineshapes.TheMELvariesasafunctionoftheCothicknessandreachestheoptimalvalueat10nm.TheMELandMCdependenceonvoltageandtemperatureisalsoinvestigated.Theelectron-holepairmodelandthespin-polarizedinjectionmechanismareusedtounderstandtheexperimentalresults.