简介:在这份报纸,活跃光学和合作焦点,分割的镜子的试验性的系统被造。第一,分割的镜子的支持结构被设计,为分割的镜子的试验性的系统满足要求被模拟验证。在这个系统,大散焦并且倾斜/付小费给分割的镜子的错误被观察密度调整并且基于等斜的干扰理论干扰穗形成对照直到defocus并且倾斜/付小费给错误在Shack-Hartmann的侦探范围。然后,Shack-Hartmann被用来测量他们,他们被致动器调整。致动器被活跃光学控制为分割的镜子的好合作焦点认识到靠近环的调整和维护。并且干扰穗被利用验证Shack-Hartmann的侦探精确。在分割的镜子调整的合作焦点以后,倾斜/付小费给剩余表面错误比RMS好;defocus剩余表面错误比RMS好。
简介:CO2capturewithionicliquids(ILs)hasattractedmanyattentions,andmostworksfocusedonabsorptionabilityatambienttemperatures,whileseldomresearchwasconcernedatelevatedtemperatures.ThisnotonlylimitstheCO2absorptionapplicationatelevatedtemperature,butalsothedeterminationoftheoperationconditionoftheCO2desorptiongenerallyoccurringathighertemperature.ThisworkmainlyreportedCO2solubilitiesinILsatelevatedtemperaturesandrelatedpropertieswerealsoprovided.1-alkyl-3-methylimidazoliumbis(trifluoromethylsulfonyl)imide([CnMIm][Tf2N])ILswereselectedasphysicalabsorbentsforCO2captureinthisworkduetotheirrelativehigherCO2absorptioncapacitiesandgoodthermalstabilities.Thelong-termstabilitytestsshowedthat[CnMIm][Tf2N]isthermallystableat393.15Kforlongtime.CO2solubilitiesin[CnMIm][Tf2N]weresystematicallydeterminedattemperaturesfrom353.15Kto393.15K.ItdemonstratedthatCO2solubilityobviouslyincreaseswiththeincreaseofpressurewhileslightlydecreaseswithincreaseoftemperature.Asthelengthofalkylchainonthecationincreases,CO2solubilityinILsincreases.Additionally,thethermodynamicpropertiesincludingtheGibbsfreeenergy,enthalpy,andentropyofCO2werealsocalculated.
简介:Asignalwaveformrecoverymethodbasedonthecoprimearrayisinvestigatedtoextractthewaveformofthedesiredsignalfromspatialinterferencesinnarrowbandscenarios.Thedirectionofarrivals(DOAs)ofthedesiredsignalandinterferencesignalsareestimatedwiththecompressivesensingapproachbasedonanglegrids,andthesignalpowertogetherwiththenoisepowerareestimated.Thereafter,amodifiedsteepestdescent(SD)methodisderivedtorecoverthewaveformofthedesiredsignalandinterferencesutilizingtheestimatedpoweranddirections.Therecoveredwaveformofthedesiredsignalistheoutputoftheproposedmethod.Thesituationinwhichthesignalsarenotonthepredefinedanglegridsisalsoconsidered.TheDOAsestimatedpredefinedanglegridsisalsoconsidered.TheDOAsestimatedlikelihood(ML)angleestimation.Comparedtotheexistingbeamformingmethodsonco-primearray,theproposedmethodcanobtainthewaveformofthedesiredsignal.Simulationresultsdemonstratethattheproposedmethodcanachievegoodperformanceinsignalwaveformrecoveryandoutputsignaltonoiseratio.
简介:Co-electrolysisofCO2andH2Ousinghigh-temperaturesolidoxideelectrolysiscells(SOECs)intovaluablechemicalshasattractedgreatattentionsrecentlyduetothehighconversionandenergyefficiency,whichprovidesopportunitiesofreducingCO2emission,mitigatingglobalwarmingandstoringintermittentrenewableenergies.AsingleSOECtypicallyconsistsofanionconductingelectrolyte,ananodeandacathodewheretheco-electrolysisreactiontakesplace.Thehighoperatingtemperatureanddifficultactivatedcarbon-oxygendouble-bondofCO2putforwardstrictrequirementsforSOECcathode.Greateffortsarebeingdevotedtodevelopsuitablecathodematerialswithhighcatalyticactivityandexcellentlong-termstabilityforCO2/H2Oelectro-reduction.Thesofarcathodematerialdevelopmentisthekeypointofthisreviewandalternativestrategiesofhigh-performancecathodematerialpreparationisproposed.UnderstandingthemechanismofCO2/H2Oelectro-reductionisbeneficialtohighlyactivecathodedesignandoptimization.Thusthepossiblereactionmechanismisalsodiscussed.Especially,amethodincombinationwithelectrochemicalimpedancespectroscopy(EIS)measurement,distributionfunctionsofrelaxationtimes(DRT)calculation,complexnonlinearleastsquare(CNLS)fittingandoperandoambientpressureX-rayphotoelectronspectroscopy(APXPS)characterizationisintroducedtocorrectlydisclosethereactionmechanismofCO2/H2Oco-electrolysis.Finally,differentreactionmodesoftheCO2/H2OcoelectrolysisinSOECsaresummarizedtooffernewstrategiestoenhancetheCO2conversion.Otherwise,developingSOECsoperatingat300-600°CcanintegratetheelectrochemicalreductionandtheFischer-TropschreactiontoconverttheCO2/H2Ointomorevaluablechemicals,whichwillbeanewresearchdirectioninthefuture.
简介:ReducingtheanthropogenicCO2emissionsfromfossilresourcecombustionandhumanactivitieshasbecomeoneofthemajorchallengeswearefacingtoday.BeyondthosepracticalapplicationsfortheutilizationofCO2,suchasthesynthesisofsalicylicacid,methanol,urea,NaHCO3-Na2CO3chemicalsandrecentlydevelopedpolycarbonatesynthesis,scientistsarestillseekingnewmaterialsandtechnologiesforefficientcapture,
简介:TheeffortonelectrochemicalreductionofCO2tousefulchemicalsusingtherenewableenergytodrivetheprocessisgrowingfastrecently.Inthisreview,weintroducetherecentprogressesontheelectrochemicalreductionofCO2insolidoxideelectrolysiscells(SOECs).Athightemperature,onlyCOisproducedwithhighcurrentdensitiesandFaradicefficiencywhilethereactoriscomplicatedandabettersealingtechniqueisurgentlyneeded.Thetypicalelectrolytessuchaszirconia-basedoxides,ceria-basedoxidesandlanthanumgallates-basedoxides,anodesandcathodesareintroducedinthisreview,andthecathodematerials,suchasconventionalmetal–ceramics(cermets),mixedionicandelectronicconductors(MIECs)arediscussedindetail.Inthefuture,togainmorevalue-addedproducts,theelectrolyte,cathodeandanodematerialsshouldbedevelopedtoallowSOECstobeoperatedattemperaturerangeof573–873K.Atthosetemperatures,SOECsmaycombinetheadvantagesofthelowtemperaturesystemandthehightemperaturesystemtoproducevariousproductswithhighcurrentdensities.
简介:Inthisstudy,wepresentanewmethodtocomputeinternalco-seismicdeformationsofahomogeneoussphere,basedonourpreviousapproach(Dongetal.2016).Inpracticalnumericalcomputations,weconsiderastrike-slippointsourceasanexample,andcomputetheverticalco-seismicdisplacementondifferentinternalsphericalsurfaces(includingtheEarthsurface).Numericalresultsshowthattheinternalco-seismicdeformationsaregenerallylargerthanthatontheEarthsurface;especially,themaximumco-seismicdisplacementappearsaroundtheseismicsource.Theco-seismicdisplacementsareoppositeinsignfortheareasoverandbeneaththepositionoftheseismicsource.Theresultsalsoindicatethatthecurvatureeffectoftheinternaldeformationisprettylarge,andlargerthanthatontheEarthsurface.Theresultsindicatethatthedislocationtheoryforasphereisnecessaryincomputinginternalco-seismicdeformations.
简介:Wesynthesizedonequaternaryammoniumpolymericionicliquids(PILs)P[VBTHEA]ClandthreeimidazoliumPILsofP[VEIm]Br,P[VEIm]BF4,P[VEIm]PF6byfree-radicalpolymerizationinsolution.ThesePILswerecharacterizedbyFT-IR,1H-NMR,13C-NMR,TGA,XRDandSEM.TheirCO2adsorptioncapacitiesweremeasuredunderdifferentpressuresandtemperaturesbyconstant-volumetechnique.ItwasobservedthatquaternaryammoniumPILsofP[VBTHEA]ClhavehigheradsorptioncapacityforCO2thanthoseimidazoliumPILs,followingP[VBTHEA]Cl>P[VEIm]PF6>P[VEIm]BF4>P[VEIm]Br,whichmaybeascribedtohigherpositivechargedensityonammoniumcationthanthatonimidazoliumcationandthusstrongerinteractionwithCO2,consistentwiththeresultsfromdual-modeadsorptionmodelthatammoniumPILshavemuchhigherCO2bulkabsorptionthanimidazoliumPILs.CO2adsorptioncapacityofP[VBTHEA]Clis9.02mg/gunder295Kand1bar,whichiscomparabletothatofsomeotherPILs,andismuchhigherthanthatofthecorrespondingILsmonomer.ThesePILshavegoodadsorptionselectivityforCO2overN2andregenerationefficiency.
简介:Exosomes是endocytic起源的nanoparticles,由由他们调制cell-to-cell通讯的能力的优点正在吸引增加的注意的无数房间人口藏匿了。他们也在许多免疫学的问题正在吸引注意,包括autoimmunity和,特别地调整cytokine和chemokine激活的他们的能力。主要胆汁的肝硬化(PBC)被认为一个模型自体免疫疾病,它对胆汁的上皮的房间有高度集中的细胞毒素的回答。我们与PBC和30健康控制(HC)从29个病人从血浆孤立exosomes,并且用一个前vivo系统在mononuclear房间人口在co-stimulatory分子表示和cytokine生产上学习了这些exosomes的效果。我们也与HCexosomes相比在PBC识别了microRNA(miRNA)人口。我们此处报导尽管exosomes不改变cytokine生产,他们显著地确实在介绍抗原的人口上改变co-stimulatory分子表示。进一步,我们在CD14+单核白血球上表明了那CD86起来调整的表情,而在CD11c+上起来调整的CD40由从有PBC的病人的exosomes的树枝状的房间。另外,有在有PBC的病人的传播exosomes的miRNA表示的差别。这些数据基于co-stimulatory分子玩的观察有重要重要性在T房间激活的规定的一个微分角色。我们的观察显示从PBC的异常exosomes有选择地在介绍抗原的房间的不同子集导致co-stimulatory分子的表示。这些改变可以在自体免疫的肝疾病的致病包含。
简介:Thomsonscatteringimaging(TSI)isproposedandexperimentallydemonstratedtoobservethefinestructureofthelaserwakefield.ByThomsonscatteringaco-propagatinglaserpulse,weobtainc/earimagesindicatingthatthewakefieldislikeanacalephswimmingbehindthepumplaser.Thewavelengthofthewakefieldobservedatdifferentelectrondensitiesagreeswellwiththetheory.Sincenomathematicstransformationisinvolved,TSIcouldbepotentiallyusedasanonlinemonitorforfuture'tabletop'plasmaaccelerators.
简介:Amine-silicacompositematerialsforpost-combustionCO2capturehaveattractedconsiderableattentionbecauseoftheirhighCO2uptakeatlowCO2concentrations,excellentCO2captureselectivityinthepresenceofmoisture,andlowerenergyrequirementsforsorbentregeneration.Thisreviewdiscussestherecentadvancesinamine-silicacompositesforCO2capture,includingadsorbentpreparationandcharacterization,CO2captureunderdryandmoistureconditionsatdifferentCO2partialpressures,sorbentregeneration,andstabilityaftermanycyclicsorption-desorptionruns.
简介:TheadsorptionofCOonPtgroupmetals,asamostfundamentalelementaryreactionstep,hasbeenwidelystudiedincatalysisandelectrocatalysis.Particularly,thestructuresofCOonPt(111)havebeenextensivelyinvestigated,owingtoitsimportancetobothfundamentalandappliedcatalysis.Yet,muchlessisknownregardingCOadsorptiononaPt(111)surfacemodulatedbysupportedoxidenanostructures,whichisofmorerelevancetotechnicalcatalysis.Wethusinvestigatedthecoverage-dependentadsorptionofCOonaPt(111)surfacepartiallycoveredbyFeOxnanostructures,whichhasbeendemonstratedasaremarkablecatalystforlow-temperatureCOoxidation.Wefoundthat,duetoitsstrongchemisorption,thecoverage-dependentstructureofCOonbarePtisnotinfluencedbythepresenceofFeOx.But,oxygen-terminatedFeOxnanostructurescouldmodulatethediffusivityofCOattheirvicinity,andthusaffecttheformationoforderedCOsuperstructuresatlowtemperatures.Usingscanningtunnelingmicroscopy(STM),weinspectedthediffusivityofCO,followedthephasetransitionsofCOdomains,andresolvedthemoleculardetailsofthecoverage-dependentCOstructures.OurresultsprovideafullpictureforCOadsorptiononaPt(111)surfacemodulatedbyoxidenanostructuresandshedlightsontheinter-adsorbateinteractiononmetalsurfaces.