简介:TheballmillingofFe-24MnandFe-24Mn-6Simixedpowdershasbeenperformedbythehighenergyballmillingtechnique.ByemployingX-raydiffractionandMoessbauermeasurements.Theccmpositionevolutionduringthemillingprocesshasbeeninvestigated.TheresultsindicatetheformationofparamagneticFe-MnorFe-Mn-Sialloyswithametastablefccphaseasfinalproducts.whichimplythattheFeandMnproceedaco-diffusionmeenanismthroughthesurfaceoffragmentedpowders.Thethermalstabilityandcompositionevolutionoftheas-milledalloyswerediscussedcomparingwiththebulkalloy,.
简介:ThestructureandhydridingperformanceofLa0.6Nd0.4Ni4.8Mn0.2Cux(x=0~0.4)alloyswereinvestigatedinordertodevelopsuitablematerialsformetalhydrideairconditioner.TheeffectofCuadditiononthecrystalstructure,equilibriumpressure,hydrogencapacityandhysteresisaswellashydrogenabsorption/desorptionkineticsweresystematicallystudiedbyusingthemeasurementofP-Cisotherms,X-raydiffractionandscanningelectronmicroscopy.AstheamountofCuincreases,theplateaupressureincreasesandhydrogenabsorption/desorptionkineticsisimproved,buttheeffectivehydrogenstoragecapacitydecreases.Itisshownthatvariationsinthebasalplaneparameteracanbeusedasanindicationfortheplateaupressurechanges.Withtheincreaseofparametera,theplateaupressuredecreases.ForLa0.6Nd0.4Ni4.8Mn0.2Cux(x=0~0.4)alloysthereisarelationshipbetweentheeffectivehydrogenstoragecapacitiesandtheratiosoftheirunitcellparameterscanda.Theeffectivehydrogenstoragecapacitydecreaseswithincreaseofa/c.
简介:ThestabilityconstantsofthebinarycomplexesofMn2+withnicotinamide(NA)weredeterminedfrompotentiometricpHtitrationsdataat15.0,25.0and35.0oCandI=0.1,0.2,0.4molL-1(NaClO4).Theformationofbinary1:1,1:2NA-Mncomplexesatthreedifferenttemperaturesandtheinfluenceofthreedifferentionicstrengthontheirstabilitywerereported.Thethermodynamicparameters(△Gof,△Sof,△Hof)forthecomplexformationreactionwereestimatedfromstabilityconstantatdifferenttemperatures.
简介:张力爬精细的Fe-Mn二进制合金containing0.42-1.21wt.%Mn的行为从房间温度在温度范围被调查了到475Kunder10-50MPa。张力的测试以紧张率在uniaxail负担下面以经常的小标题速度被执行10(-4)s(-1)。压力代表和激活精力决心澄清变丑机制。稳定的状态的获得的变化爬关于为Fe-Mn二进制合金的应用压力的率在大约20MPa展出二不同政体,显示一个可能的变化在爬机制。平均压力代表是约2.2,它是在合金滑动的谷物boundry的一个特征。为塑料流动的激活精力从135~92kJ/mol变化,取决于Mn内容。
简介:Sinceithasexcellenttensilestrength,thequenchingandpartitioning(Q&P)treatedsteelhasbeenwidelyacclaimed.SomeresearchediscurrentlybeingconductedonQ&Psteel,butQ&Ptechniquesandrelatedmechanismshavebeenmostlyresearchbasedonconventionaltransformation-inducedplasticity(TRIP)steel.ThisstudyresearchestheeffectofMnonthepropertiesofQ&Psheetsteel.TwokindsofsteelsheetwithdifferentlevelsofMncontent(1.46%Mnand2.75%Mn)areinvestigated.Afterbeingfullyannealed,thesteelsheetswerequenchedtoatemperaturebetweenMsandMf.Allocationtreatmentthencausedthecarbontobepartitionedintotheremainingaustenite.Themicrostructureandtensilepropertieswereanalyzed.TheresultsshowthattheincrementofMncontentcanincreasethestabilityofthesteelanddecreasethesensitivityofthequenchingtemperature(QT).TheresultsalsoindicatethatincreasingthelevelofMncaneffectivelysuppresstheformationofbainite.
简介:ThegrainrefiningmechanismofC-Mnsteelsheetoncompactstripproduction(CSP)linewasinvestigatedinthisstudy.Thegrainwasabout100μmafterF1passanddecreasedallthewayoftherollingprocess(F2-F6)to15μm.Repeatedphasetransformationexperimentwasconductedtothesteelforgrainrefinement.Thephasetransformationat860℃and920℃canrefinethegrainsizeto7.5μm.
简介:[摘 要]财务风险是每一个公司都不可避免的风险问题,其对企业的影响及危害性是巨大的,本文以MN公司为对象进行了深入研究,在对MN公司概况有了基本了解之后,对MN公司的筹资活动风险、投资活动风险、经营活动风险等财务风险进行了识别,分析了MN公司目前的财务风险控制状况,为下文针对MN公司存在的财务风险问题,提出了相应的财务风险控制建议。
简介:Mg-Al-Pb合金是一种新开发的海水激活电池材料。采用熔炼浇注法制备Mg-6Al-5Pb-0.5Mn系列合金和Mg-6Al-5Pb合金。其中,Mg-6Al-5Pb-0.5Mn系列合金是以Al-15%Mn、Al-30%Mn和Al-50%Mn中间合金为添加剂制备的。采用金相显微镜和扫描电子显微镜表征其组织,采用电化学方法、析氢法和失重法研究其性能。结果表明:以Al-50%Mn中间合金为添加剂制备的Mg-6Al-5Pb-0.5Mn合金具有最负的放电电位(-1.66V),最小的腐蚀电流密度(7μm/cm2)和自腐蚀速率(0.51mg·h-1·cm-2)。这可能是因为Al11Mn4相的存在,不仅有利于腐蚀产物的脱落和增大电化学反应面积,而且也提高电化学活性。
简介:Deformation-inducedmicrostructuresofhigh-Mnaustenitesteelwasinvestigatedbymetallography,X-raydiffractionandSEM.Theε-martensiteandslip-bandsaredeformation-in-ducedonthe{111}planes,andappearasthinstraightlathswith60~80°alignmentdifferencebe-tweenthem.Itwasfoundthatε-martensiteandslipbandsarekinkedatfcctwinboundarieswiththekinkedangle35~40°.Thebandsofequilateraltriangleinthemicrostructureoftensiledeformationarepresented.
简介:Soilswerecollectedfrom2-year(2-y)and3-year(3-y)oldred-pineseedlingplotsintwotreenurseries,HaywardinthenorthandWilsoninthesouthwesternpartofWisconsinStaterespectively,andequilibratedwith0.01MCa(NO3)2)forsoilsolutionZnandMn(solu-ZnandMn),andwith0.01MCa(NO3)2+0.005MEDTAforsoilabsorbedZnandMn(ad-ZnandMn).BufferingcapacityofsoilZnandMn(b-ZnandMn)wasobtainedfromtheratioofad-ZnandMntothesolu-ZnandMn.Theconcernedtracesinpineseedlingneedles(ndls),stems(sts)androots(rts)weresimultaneouslymeasured.Theresultsobtainedshowthat:About60%ofsolu-andad-Znrangedfrom0.2to0.4andfrom1to2μg/gsoilrespectively.About70%ofb-Znwaswithin3-10.Thehighestcontentofsolu-Zncomparedwiththelowestshowedadiscrepanceofmorethan10-fold.ThetwoformsofsoilZnwerecommonlyhigherinWilsonthaninHaywarkNursery.About80%ofsolu-,ad-andb-Mnwerewithin3-10,5-5.8μg/gsoiland1-2respectively.Influenceoflowbufferingcapacityonsolu-ZnandMnwasabout20timesstrongerthanthatofthehigh.TheE-value,aratioofaccumulatedZnandMninneedlestothoseinthesoilsolution,isprovedtobe:E-Zn>E-Mn;E-sts>E-ndlsorE-rts;andE-2y>E-3y.Curvilinearand/orlinearcorrelationsbetweensoilsolu-,ad-andb-ZnandMnandndls-,sts-,rts-ZnandMnwereatverysignificantorsignificantlevels.Forpredictingndls-ZnandMn,tworealizableandsimplemodelsfromtworegressionequationswereestablishedthroughtheselectionofrelatedparametersanddependentvariables.BinaryregressionanalysisbasicallyeliminatedtheinfluenceofsoilpHonthepredictionofZnandMninneedles.SoilpHwasthusthoughttobeexcludedfromthemodel.