简介:ThepreparationofhybridmesoporousMCM-48graftedbyvinylgroupviapost-graftingprocesswasreportedandstudiedbyX-raydiffraction,BETand29SisolidMASNMR.Anorganicβ-diketonateEuropiumcomplexthecorrespondingluminescencepropertywascharacterized.
简介:ThispaperderivestheLindellformulabasedonthegeneralizedvariationalprinciple.ForthecomplexdielectricconstantmeasurementofasmalllossydielectricrodwithRayleigh-Ritzmethod,anaccuratevariationalanalysisisgiven.Theconceptofcomplexfrequencyisintroducedingeneral,andthestabilityofthesolutionisdiscussed.Comparingwiththeresultofperturbationmethod,itisconcludedthatthedeviationofperturbationalgorithmshouldbetakenintoconsideration.
简介:Pd/C向polyketones(PK)的形成催化的公司和苯乙烯的copolymerization在N-valeronitrile-N-methylimidazoliumhexafluorophosphate被学习([C4CNmim]+PF6)中等。综合PK被Fourier变换描绘红外线(FTIR),元素的分析,13C-nuclear磁性的回声(13C-NMR),微分扫描热量测定(DSC),thermogravimetric分析(TGA)和胶化浸透层析(GPC)。Pd/C催化剂的表面上的支持的离子的液体电影能阻止产品用金属离子由于它的化学稳定性和弱协作能力盖住活跃的碳的洞,并且高效地因此改进催化活动。在催化剂的催化活动和PK的分子的重量的离子的液体的不同数量的效果被讨论。离子的液体的用法什么时候是10wt%(0.1g离子的液体/1g活跃的碳搬运人)并且Pd2+的理论内容是5wt%(0.05gPd2+/1g活跃的碳搬运人),最高催化的活动2963.64gSTCO/(gPd訐?訐??
简介:ThereisabeltofmetamorphiccorecomplexesinthewesternmarginoftheYangtzecraton.ThegeologicalsettingofthebeltissimilartothatoftheCordilleranmetamorphiccorecomplexes.AtypicaloneinthisbeltistheJianglangmetamorphiccorecomplex,whichhasaconfigurationconsistingofthreelayers:acorecomplexconsistingofMesoproterozoicschistsequence,aductilemiddleslabconsistingofPaleozoicmeta-sedimentary-basaltcharacterizedbythedevelopmentof"foldinglayer"andanuppercoverconsistingofXikangGroupwhichhassufferedbothbucklingandflattening.AdetachmentfaultdevelopedalongthecontactboundarybetweenthecoverandbasementcausestheomissionofUpperSinianandCambrianatthebaseofcover.Alotofnormalductileshearzonesdevelopedinthecovercausesthethinningofit.Allthefeaturesshowthattheearlyextensionresultsinthethinningofcrust,buttheformationofthedomeandexposureofbasementrocksmaybetheresultsofsuperimp
简介:TheradiatedfieldsGaussianDistributedAperture(GDA)canbeapproximatelyanalyzedbytheComplexRayMethod(CRM).Inthisarticle,theradiatedfieldsderivedintermsofplanewavespectrumintegralareusedasstandard,andtheerrorsourceofthereplacementbycomplexrayfieldsisfound.WithdiscussionsontheerrorcharacteristicsofthisCRMapproximation,conclusionsaredrawnwhichareexpectedtobehelpfulinapplicationsofCRM.
简介:Themainpurposeofthispaperistostudytheproblemsontheexistenceofalgebraicsolutionsforsomesecond-ordercomplexdifferentialequationswithentirealgebraicfunctionelementcoefficients.Severaltheoremsontheexistenceofsolutionsareobtained,whichperfectthesolutiontheoryoflinearcomplexdifferentialequations.
简介:ThetreatmentoftheGacuncomplexCu-PbbulkconcentratewithhighZn,Ag,etc.,byoxygenpressureacidleachingwasstudied.Theprimarycopperandleadmineralsintheconcentratearetetrahedriteandgalena.Thetreatmentoftetrahedritewasrarelystudied,andmostofsilveroccurredinthemineraltoo.Theoptimumoperatingparametersofoxygenpressureacidleachingwereestablishedbyconditionaltests.Undertheseparameters,theresultofpilotscaletestshowedthattheleachingpercentagesofcopperandzincwereseparatelyashighas98.9wt.%and94.9wt.%,whileleadandsilverweretransformedintosulfateandsulfideprecipitations,respectively.Thecopperandzincinlixiviumwerereclaimedbyextraction-electrowinningandpurification-electrowinning,respectively,andtheleadandsilverintheresiduewerereclaimedseparatelybycarbonatetransformation-silicofluoricacidleachingandthiourealeaching.
简介:OneofthemajoraromaticsprojectsatthePetroChinaUrumqiPetrochemicalCompany—theconstructionof1.0Mt/aparaxylene/aromaticsintegratedunitwasofficiallykickedoffonMay1,2008inUrumqi.Theinvestmentinthisunittotals3.867billionRMB,makingthisunitthelarg-estsingle-seriesone-million-ton-classaromaticsintegratedunitamongtheworld'ssimilarunits.
简介:Anovelhybridapproachforearthquakelocationisproposedwhichusesacombinedcoarseglobalsearchandfinelocalinversionwithaminimumsearchroutine,plusanexaminationoftherootmeansquares(RMS)errordistribution.ThemethodexploitstheadvantagesofnetworkraytracingandrobustformulationoftheFréchetderivativestosimultaneouslyupdateallpossibleinitialsourceparametersaroundmostlocalminima(includingtheglobalminimum)inthesolutionspace,andfinallytodeterminethelikelyglobalsolution.Severalsyntheticexamplesinvolvinga3-Dcomplexvelocitymodelandachallengingsource-receiverlayoutareusedtodemonstratethecapabilityofthenewly-developedmethod.Thisnewglobal-localhybridsolutiontechniquenotonlyincorporatesthesignificantbenefitsofourrecentlypublishedhypocenterdeterminationprocedureformultipleearthquakeparameters,butalsoofferstheattractivefeaturesofglobaloptimalsearchingintheRMStraveltimeerrordistribution.Unlikethetraditionalglobalsearchmethod,forexample,theMonteCarloapproach,wheremillionsoftestshavetobedonetofindthefinalglobalsolution,thenewmethodonlyconductsamatrixinversiontypelocalsearchbutdoesitmultipletimessimultaneouslythroughoutthemodelvolumetoseekaglobalsolution.ThesearchisaidedbyinspectionoftheRMSerrordistribution.Benchmarktestsagainsttwopopularapproaches,thedirectgridsearchmethodandtheoct-treeimportantsamplingmethod,indicatethatthehybridglobal-localinversionyieldscomparablelocationaccuracyandisnotsensitivetomodestlevelofnoisedata,butmoreimportantlyitofferstwo-orderofmagnitudespeed-upincomputationaleffort.Suchanimprovement,combinedwithhighaccuracy,makeitapromisinghypocenterdeterminationschemeinearthquakeearlywarning,tsunamiearlywarning,rapidhazardassessmentandemergencyresponseafterstrongearthquakeoccurrence.
简介:TwoEu(Ⅲ)complexes,(tris-4,4,4-trifluoro-1-phenyl-1,3-butanedione)(1,10-phenanthroline)europium(Ⅲ)[Eu(tpb-H)3(phen)]and(tris-4,4,4-trifluoro-1-phenyl-1,3-butanedione)(2,2'-bipyridine)europium(Ⅲ)[Eu(tpb-H)3(bipy)]weresynthesizedfrombi-dentaloxygenandnitrogenligands.LuminescentpolymerswerefabricatedbyincorporatingdeuteratedEu(Ⅲ)complexesinpoly(methylmethacrylate)(PMMA)matrixes.LuminescentPMMAcontainingEu(tpb-D)3(phen)exhibitedrelativelyhigherquantumyield[Φ,(48.7±4)%],fasterradiationrate(kr,7.49×102s-1),sharperredemission[fullwidthathalfmaximum(FWHM),6.3nm]andlargerstimulatedemissioncross-section(SEC,1.29×10-20cm2).ThevalueofSECisthesameorderasthatofNd-glasslaserforpracticaluse.Additionally,thethermalpropertiesofEu(tpb-H)3(phen),Eu(tpb-H)3(bipy),Eu(tpb-D)3(phen)-PMMA,andEu(tpb-H)3(bipy)PMMAwerestudied,indicatingthattheEu(Ⅲ)complexesandluminescentPMMAcanbeusedforalong-termperiodinhightemperatureenvironment.PreparedluminescentpolymersincludingEu(tpb-D)3(phen)havepromisingapplicationsinnovelorganicEu(Ⅲ)devices,suchasthehigh-powerlasermaterialsandopticalfibers.
简介:AIMTo在在为复杂网膜的detachment.METHODSWe经历retinectomy的病人的硅酮油(ROSO)的移动执行了为复杂网膜的分开在retinectomy以后经历了ROSO的病人的回顾的盒子笔记评论以后,评估功能的结果。有不到6mo的病人列在后面在上面并且周期性的网膜的分开追随者ROSO是excluded.RESULTSThirty--六个病人被包括。吝啬的最好改正的视觉尖酸(BCVA)pre-ROSO是1.13logMAR(SD0.5)。吝啬的BCVA3mo追随者ROSO是1.16logMAR(SD0.53),6mo追随者ROSO1.13(SD0.63),和跟随ROSO1.18(SD0.69)的12mo。在在ROSO以后的12mo,BCVA在38.9%病人改善了,在25%仍然保持未改变,并且尽管在在在3点的ROSO以后的BCVA没有统计重要差别,在36.1%败坏了,6并且12mo(P=0.93)。retinectomy的尺寸从15°;到270°;(SD53)并且没影响.CONCLUSIONThere是的视觉结果(P=0.11)在在pre-和柱子之间的BCVA的没有统计上重要的差别--为复杂网膜的分开的ROSO后面的retinectomy。在与retinectomy的尺寸有关的视觉结果没有统计差别。
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