简介:Asimplemethodisappliedtocalculatingtheisotopeshifts(ISs)on5S1/2→4D3/2,5/2transitionsof87,88Sr+.FirstwehavecalculatedtheISsoflowertransitionsonaseriesofalkali-likesystemssuchasB2+,Ca+andBa+,whichareinagreementwithotherworks.ThentheISson5S1/2→4D3/2,5/2transitionsof87,88Sr+,whichareusefultostudytheSr+opticalfrequencystandard,areevaluated.
简介:Inthispaper,weinvestigatethecouplingofnaturalboundaryelementandfiniteelementmethodsofexteriorinitialboundaryvalueproblemsforhyperbolicequations.Thegoverningequationisfirstdiscretizedintime,leadingtoatime-stepscheme,whereanexteriorellipticproblemhastobesolvedineachtimestep.Second,acircularartificialboundaryFRconsistingofacircleofradiusRisintroduced,theoriginalprobleminanunboundeddomainistransformedintothenonlocalboundaryvalueprobleminaboundedsubdomain.AndthenaturalintegralequationandthePoissonintegralformulaareobtainedintheinfinitedomainΩ2outsidecircleofradiusR.Thecoupledvariationalformulationisgiven.Onlythefunctionitself,notitsnormalderivativeatartificialboundaryΓR,appearsinthevariationalequation,sothattheunknownnumbersarereducedandtheboundaryelementstiffnessmatrixhasafewdifferentelements.Suchacoupledmethodissuperiortotheonebasedondirectboundaryelementmethod.Thispaperdiscussesfiniteelementdiscretizationforvariationalproblemanditscorrespondingnumericaltechnique,andtheconvergenceforthenumericalsolutions.Finally,thenumericalexampleispresentedtoillustratefeasibilityandefficiencyofthismethod.
简介:Anewcompoundbasedonpolyoxovanadate[{Ni(en)2}2Sb8V14O42]·5.5H2O(en=ethylenediamine)(1)wassynthesisedhydrothermallyasblackrhombuscrystals.Compound1crystallizedinthemonoclinicsystemwithspacegroupP21/n,Z=4,a=1.46953(9)nm,b=1.28623(8)nm,c=1.76008(11)nm,β=105.7230(10)°.Intheasymmetricunit,cluster{Sb8V14O42}canbeconsideredasanSbderivativeofthe{V18O42}unit.Each{Sb8V14O42}clusterasabuildingblockinterconnectedtofourotherneighboringunitsby{Ni(en)2}bridginggroupswhicharelinkedthroughtheterminaloxygenatomsofthepolyoxoanions,formingatwodimensionalnetwork.
简介:Theimportantintermediateforsynthesesofvariousanti-HIVnucleosideanalogues,methyl2,3-dideoxy-3-fluoro-6-O-(p-methylbenzoyl)-a-D-ribofuranoside,wassynthesizedstartingfrom2-deoxy-D-ribosein5stepswithanoverallyieldof24%.Thisstrategycanbealsousedforsynthesizingotheranalogueswithvarioussubstitutionsat3-Cposition.
简介:Theboundaryelementmethodwasimprovedforthe2Delasticcompositeswithrandomlydistributedinclusions.Thisproblemcanbereducedtoaboundaryintegralequationforamulti-connecteddomain.Further,consideringthematricesofthetractionsanddisplacementsforeachgroupoftheidenticalinclusionwerethesame,aneffectivecomputationalschemewasdesigned,sincetheordersoftheresultingmatrixequationscanbegreatlyreduced.Numericalexamplesindicatethatthisboundaryelementmethodschemeismoreeffectivethantheconventionalmulti-domainboundaryelementmethodforsuchaproblem.Thepresentschemecanbeusedtoinvestigatetheeffectivemechanicalpropertiesofthefiber-reinforcedcomposites.
简介:WediscussthenonlinearSchrdingerequationwithvariablecoefficientsin2Dgraded-indexwaveguideswithdifferentdistributedtransversediffractionsandobtainexactbrightanddarksolitonsolutions.Basedonthesesolutions,wemainlyinvestigatethedynamicalbehaviorsofsolitonsinthreedifferentdiffractiondecreasingwaveguideswiththehyperbolic,GaussianandLogarithmicprofiles.Resultsindicatethatforthesameparameters,theamplitudeofbrightsolitonsintheLogarithmicprofileandtheamplitudeofdarksolitonsintheGaussianprofilearebiggestrespectively,andtheamplitudeinthehyperbolicprofileissmallest,whilethewidthofsolitonshastheoppositecase.
简介:怪物状态在1D数组被学习了,并且许多不同怪物状态用不同模型被发现了。研究最近被扩大了到2D数组,但是仅仅到他们的阶段模型。这里,我们把它递非局部的联合的影响上的神经原和焦点的2D数组的一个nonphase模型。用广泛的数字模拟,令人惊讶地,我们发现这个系统能显示出以前观察的怪物状态的大多数类型,与以前的模型相对照,在怪物状态的仅仅或一些类型能在每个模型被观察的地方。我们也发现这个模型能显示出象gridding那样的一些特殊像怪物的模式和multicolumn模式,它以前仅仅在阶段模型被观察。进一步,我们在场一条有效途径,即,移开联合的一些连接,产生异构的联合,它导致多样的像怪物的模式并且甚至从一个像怪物的模式导致转变到另外一个。
简介:Two-dimensional(2D)periodicalAuandindiumtinoxide(ITO)nanocompositearrayshavebeenfabricatedbasedonaself-assemblednanospherelithographytechnique.Abutton-shapedAunanoparticlewasformedoneachhollowhemisphere-shapedITOshell.Importantly,theunderlyingformationmechanismduringthethermaltreatmenthasbeenthoroughlyexploredbycomparingstructuresresultingfromdifferentdepositionconditionsindetail.ComparedtotheAunanoparticlearrayswithoutITOshells,theAu/ITOnanocompositearraysshowedastrongerlocalizedsurfaceplasmonresonanceeffectandhigherabsorptioninthenear-infrared(NIR)region,benefitingfromthefree-electroninteractionenhancementbetweenAuandITO.Thenonlinearopticalpropertieswereinvestigatedusingamodifiedfemtosecondintensity-scansystem,andtheresultsdemonstratedAu/ITOnanocompositearrayswitharemarkabletwo-photonabsorptionsaturationeffectforfemtosecondpulsesat1030nm.TheversatileNIRopticalresponsesindicatethegreatpotentialoftheelaboratelyprepared2DperiodicalAu/ITOnanocompositearraysinmanyapplicationssuchassolarcells,photocatalysis,andnovelnanooptoelectronicdevices.
简介:Foraccuracyandrapidityofaudioeventdetectioninthemass-dataaudioprocessingtasks,agenericmethodofrapidlyrecognizingaudioeventbasedon2D-HaaracousticsuperfeaturevectorandAdaBoostisproposed.Firstly,itcombinescertainnumberofcontinuousaudioframestobean'acousticfeatureimage',secondly,usesAdaBoost.MHorfastRandomAdaBoostfeatureselectionalgorithmtoselecthighrepresentative2D-Haarpatterncombinationstoconstructsuperfeaturevectors;thirdly,analyzesthecommonalityanddifferencesbetweensubcategories,thenextractscommonfeaturesandreducesdifferentfeaturestoobtainagenericaudioeventtemplate,whichcansupporttheaccurateidentificationofmultiplesub-classesanddetectandlocatethespecificaudioeventfromtheaudiostreamaccurately.Experimentalresultsshowthattheuseof2D-Haaracousticfeaturesupervectorcanmakerecognitionaccuracy5%higherthanonesthatMFCC,PLP,LPCCandothertraditionalacousticfeaturesyielded,andcanmakethetrainingprocessing7-20timesfasterandtherecognitionprocessing5-10timesfaster,itcanevenachieveanaverageprecisionof93.38%,anaveragerecallof95.03%undertheoptimalparameterconfigurationfoundbygridmethod.Aboveall,itcanprovideanaccurateandfastmass-dataprocessingmethodforaudioeventdetection.
简介:Asupramolecular1Dferromagneticsystemwasstudiedexperimentallyaswellastheoretically.Hybriddensityfunctionaltheory(DFT)calculationswerebasedontheX-rayanalysis.TheresultsofDFTcalculationsandMcConnellmechanismhavecontributedtotheunderstandingofthefactorsgoverningtheexchangecouplingofmagnetisminthecrystalpacking.Boththeexperimentalevidenceandtheoreticalcalculationindicatethatspindensityin2-iodonitronylnitroxide(INN)radicalsconfirms1Dferromagneticchainwithinter-chainantiferromagneticinteraction.