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15 个结果
  • 简介:这研究的主要目的是与极端热的屏蔽性质开发autoclaved光水泥(ALC)材料并且调查在它的物理特征和机械性质之间的关系。通过干燥体积密度和压缩力量的测试,物理特征的关系和样品的机械性质被学习,导致有极端热的屏蔽性质的材料。扫描电子显微镜(SEM)和精力散的X光检查光谱学(EDX)被使用分析样品的微形态学、元素的作文。识别产品阶段,X光检查衍射(XRD)订婚。测试结果证明压缩力量和热系数与在混合物以内增加铝粉末被减少。作为结果,最佳的热系数和样品的压缩力量被改进到0.061有(m吗?

  • 标签: 轻质混凝土 混凝土强度 蒸压 扫描电子显微镜 X射线衍射分析 热绝缘材料
  • 简介:Anovelgraphene/Agnanoparticles(NPs)hybrid(preparedbyaphysicalmethod(PM))wasincorporatedintoelectrospunTiO2fiberstoimprovevisible-light-drivenphotocatalyticproperties.Theexperimentalstudyrevealedthatthegraphene/AgNPs(PM)hybridnotonlydecreasedthebandgapenergyofTiO2,butalsoenhanceditslightresponseinthevisibleregionduetothesurfaceplasmonresonance(SPR)effect.Inaddition,comparedwiththoseofTiO2fibersincorporatingthegraphene/AgNPshybrid(preparedbyachemicalmethod(CM)),TiO2-graphene/AgNPs(PM)fibersexhibitedahighersurfacephotocurrentdensityandsuperiorphotocatalyticperformance,i.e.,thevisible-light-drivenphotocatalyticactivitywasenhancedby2times.Themainreasonsincludealowersurfacedefectdensityofthegraphene/AgNPs(PM)hybrid,asmallerparticlesize(10nm)andahigherdispersityofAgNPs,whichpromotetherapidtransferofphotoexcitedchargecarriersandinhibittherecombinationofphotogeneratedelectronsandholes.Itisexpectedthatthiskindofternaryelectrospunfiberswillbeapromisingcandidateforapplicationsinwatersplitting,solarcells,CO2conversionandoptoelectronicdevices,etc.

  • 标签: TiO2-graphene/Ag electrospining PHOTOCATALYSIS
  • 简介:A双层TiO2nanotube数组被Ti陪衬的二拍子的圆舞阳极化在不同电解质形成。首先,在0.5wt%HF的Ti被阳极化形成薄nanotube层。以后,第二阳极化在formamide被进行基于电解质,它允许在第一下面直接成长的nanotube的第二层。从FESEM调查,我们发现第二层的厚度对应于阳极化时间,增加哪个将导致在第一层上的过多的蚀刻。第一层在阳极化过程期间保护了更低的免受氟化物腐蚀的伤害。双层TiO2nanotube数组没在甲基橘子降级实验显示出利益到photodegradation效果。

  • 标签: 二氧化钛纳米管 阳极氧化 光催化活性 紫外光 纳米管阵列 TIO2
  • 简介:Bismuth-basedSillen-Aurivilliuscompoundsarebeingexploredasefficientphotocatalystmaterialsforthedegradationoforganicpollutantsduetotheiruniquelayeredstructurethatfavourseffectiveseparationofelectron-holepairs.Inthiswork,wesynthesizedSillen-Aurivillius-relatedBi2YO4CIwiththebandgapof2.5eVbyasimplesolid-statereactionandsensitizedwithrhodiumnickel(RhNi)nanoparticles(NPs)toformtheRhNi/Bi2YO4CIheterostructure.PhotocatalyticactivitiesofBiOCI,Bi2YO4CIandtheRhNi/Bi2YO4CIheterostructurewereexaminedforthedegradationofrhodamine-6Gundervisible-lightillumination.ResultsdemonstratedthatthephotocatalyticdyedegradationefficiencyofRhNi/Bi2YO4CIheterostructuresishigherthanthoseofBiOCIandBi2YO4CI,attributedtothesynergisticmolecular-scalealloyingeffectofbimetallicRhNiNPs.Theplausiblemechanismforthedegradationofrhodamine-6Gandtheeffectiveelectron-holepairutilizationmechanismwerediscussed.

  • 标签: BiOCI Bi2YO4CI RhNi CATALYST rhodamine-6G PHOTOCATALYSIS
  • 简介:Aone-pot,solvent-thermalprocesswasusedtocreatetheultrafineZnFe2O4nanoparticlesphotocatalyst.Duringthesolvent-thermalprocess,theinsituself-formingNaClnotonlyservedasa"cage"toconfinetheiondiffusion,butalsoactedasamicroreactorfornanocrystallitegrowth.Anaverageparticlesizeof~10nmandahigh-specificsurfaceareaof~112.9m2/gwereobservedfortheultrafineZnFe2O4nanoparticlesOwingtothesynergisticeffectofultrafineparticlesize,thefullutilizationofthevisiblelightregionandhighconductionband(CB)position,ultrafineZnFe2O4photocatalystdisplayedanefficientphotocatalyticCO2reductionundervisiblelightillumination.Besides,theultrafineZnFe2O4photocatalystshowedhighproductionselectivityforCH3CHOandC2H5OHgenerationinaqueousCO2/NaHCO3solution.Thisworkmayprovideanewideaforthesynthesisofnewhigh-efficiencyphotocatalysts.

  • 标签: ULTRAFINE NANOPARTICLES Photocatalytic CO2 reduction Visible
  • 简介:WithFe(NO3)39H2OandBi(NO3)35H2Oasrawmaterials,differentsillenite-typecompoundsandelementalbismuthwerepreparedbyafacileone-potsolvothermalmethodusingH2O,C2H5OH,(CH2OH)2andC3H8O3assolvents,respec-tively.Thestructure,morphology,elementalcompositionsandpropertiesofsampleswereexaminedbyXRD,SEM,TEM,ICP,XPS,N2adsorptionanddesorption,UV-visDRSandPL.ThephotocatalyticactivitiesofdifferentsampleswereevaluatedbythephotodegradationofRhBundervisible-lightirradiation(λ>400nm),andresultsshowthatBi36Fe2O57preparedusingC2H5OHasthesolventownstheoptimumperformance.Inordertoexplorethereactionmechanism,anadditionalexperimentwasdesignedtoinvestigatethemainactivespeciesduringthephotodegradationprocessviadissolvingdifferenttrappingagentsinthereactionsolutionbeforelightirradiation.TheresultsshowthatsuperoxideradicalanionsplayamajorroleinthissystemsincetheRhBdegradationwassignificantlysuppressedaftertheadditionofbenzoquinone.

  • 标签: PHOTOCATALYSIS sHlenite ELEMENTAL Bi Bi36Fe2O57
  • 简介:AseriesofCd1-xZnxS/K2La2Ti3O10compositesweresynthesizedviaasimpleco-precipitationmethod.ThepreparedsampleswerecharacterizedbyX-raydiffraction(XRD),scanningelectronmicroscopy(SEM),X-rayenergydispersivespectroscopy(EDX),ultraviolet-visiblediffusereflection(UV-Vis),X-rayphotoelectronspectroscopy(XPS)andphotoluminescence(PL)measurements.ThecompositestructuresconsistedofCd1-xZnxSnanoparticlesevenlydistributedonthesurfaceofK2La2Ti3O10.TheabsorptionedgeofK2La2Ti3O10shiftedtothevisiblelightregionuponintroductionoftheCd1-xZnxSnanoparticles.Thephotocatalyticactivitiesofthecatalystswereevaluatedbyhydrogenproductionundervisiblelightirradiation.ThepreparedCd0.8Zn0.2S(30wt%)/K2La2Ti3O10exhibitedhigherphotocatalyticactivity,evolving6.92mmol/gH2undervisiblelightirradiationfor3h.ThepromotedphotocatalyticactivityofthecompositeswasattributedtothesynergisticeffectbetweenCd1-xZnxSandK2La2Ti3O10,whichresultedinenhancedseparationofphotogeneratedelectronsandholes.

  • 标签: Cd1-xZnxS/K2La2Ti3O10 COMPOSITES PHOTOCATALYSIS hydrogen evolution WATER