简介:TielingValveGroupSpecialValveCo.,Ltd,formerlycalledExportFactoryoftheTielingValveWorks,TielingValveWorkswasestablishedin1935,oneofleadingenterprisesoftheMinistryofMachinery&IndustryoftheNationwithahistoryofmorethaneightyyearsandhasbeenfamousformanufacturingoflowpressureandlargesizevalves.In1997,theWorkswasreformedandtheExportFactorywasco-
简介:Asignalwaveformrecoverymethodbasedonthecoprimearrayisinvestigatedtoextractthewaveformofthedesiredsignalfromspatialinterferencesinnarrowbandscenarios.Thedirectionofarrivals(DOAs)ofthedesiredsignalandinterferencesignalsareestimatedwiththecompressivesensingapproachbasedonanglegrids,andthesignalpowertogetherwiththenoisepowerareestimated.Thereafter,amodifiedsteepestdescent(SD)methodisderivedtorecoverthewaveformofthedesiredsignalandinterferencesutilizingtheestimatedpoweranddirections.Therecoveredwaveformofthedesiredsignalistheoutputoftheproposedmethod.Thesituationinwhichthesignalsarenotonthepredefinedanglegridsisalsoconsidered.TheDOAsestimatedpredefinedanglegridsisalsoconsidered.TheDOAsestimatedlikelihood(ML)angleestimation.Comparedtotheexistingbeamformingmethodsonco-primearray,theproposedmethodcanobtainthewaveformofthedesiredsignal.Simulationresultsdemonstratethattheproposedmethodcanachievegoodperformanceinsignalwaveformrecoveryandoutputsignaltonoiseratio.
简介:Co-electrolysisofCO2andH2Ousinghigh-temperaturesolidoxideelectrolysiscells(SOECs)intovaluablechemicalshasattractedgreatattentionsrecentlyduetothehighconversionandenergyefficiency,whichprovidesopportunitiesofreducingCO2emission,mitigatingglobalwarmingandstoringintermittentrenewableenergies.AsingleSOECtypicallyconsistsofanionconductingelectrolyte,ananodeandacathodewheretheco-electrolysisreactiontakesplace.Thehighoperatingtemperatureanddifficultactivatedcarbon-oxygendouble-bondofCO2putforwardstrictrequirementsforSOECcathode.Greateffortsarebeingdevotedtodevelopsuitablecathodematerialswithhighcatalyticactivityandexcellentlong-termstabilityforCO2/H2Oelectro-reduction.Thesofarcathodematerialdevelopmentisthekeypointofthisreviewandalternativestrategiesofhigh-performancecathodematerialpreparationisproposed.UnderstandingthemechanismofCO2/H2Oelectro-reductionisbeneficialtohighlyactivecathodedesignandoptimization.Thusthepossiblereactionmechanismisalsodiscussed.Especially,amethodincombinationwithelectrochemicalimpedancespectroscopy(EIS)measurement,distributionfunctionsofrelaxationtimes(DRT)calculation,complexnonlinearleastsquare(CNLS)fittingandoperandoambientpressureX-rayphotoelectronspectroscopy(APXPS)characterizationisintroducedtocorrectlydisclosethereactionmechanismofCO2/H2Oco-electrolysis.Finally,differentreactionmodesoftheCO2/H2OcoelectrolysisinSOECsaresummarizedtooffernewstrategiestoenhancetheCO2conversion.Otherwise,developingSOECsoperatingat300-600°CcanintegratetheelectrochemicalreductionandtheFischer-TropschreactiontoconverttheCO2/H2Ointomorevaluablechemicals,whichwillbeanewresearchdirectioninthefuture.
简介:摘要在固定床反应器上研究了经铈促进的(Ce-promoted)和未经铈促进的5Co-15Ni/Al2O3,催化剂在CH4干法转化反应中的性能。虽然添加铈(2.5wt%)能够明显减少积碳,降幅可达50%,但CH4的反应速度并没有出现明显的提高(增幅小于5%),活化能也没有出现明显的改变。经铈促进的催化剂抗碳(carbonresistance)能力提高,这要归因于反应过程中铈离子稳定的多次氧化态(multipleoxidationstates)。所采用的催化剂的TPR-TPO揭示了两种类型的碳成分(carbonspecies)。第一种是活性Cα,它易于被H2气化,而且还参与氧化铈的氧化还原反应;第二种是相对的非活性Cβ,它只能被O2移除,而且不参与氧化还原反应循环。文中还提出了这种反应的双中心(dual-site)兰格缪尔(Langmuir)-Hinshelwood机理。
简介:混合氧化物(Ce0.6Zr0.4O2)由帮助微波的加热一起沉淀准备了的CeO2-ZrO2被用作支持经由早期湿的受精的方法与各种各样的CuO内容(0wt.%15wt.%)准备一系列CuO/Ce0.6Zr0.4O2催化剂。获得的CuO/Ce0.6Zr0.4O2样品被N2吸附,XRD,拉曼,TEM和H2-TPR技术,和他们的催化活动描绘因为公司氧化被调查。结果证明CuO/Ce0.6Zr0.4O2催化剂的活动被CuO的内容强烈影响,并且有10wt.%CuO的催化剂在公司氧化展出了最好的催化活动,它能在催化剂被归因于CuO,和高氧空缺集中的高分散和reducibility。
简介:摘 要:随着现代科学技术的迅猛发展,能源问题已成为当下我国乃至全社会关注的焦点问题。在研究和开发各种能量存储设备时,由于超级电容器的独特性,研究人员对其进行了广泛的研究。电极材料是超级电容器组成中的核心部件,而常见的电极材料通常由金属氧化物,碳材料以及导电聚合物来构成。金属氧化物由于具有高的理论比电容,成本低,对环境友好等特点而受到科研人员的青睐。因此,本文以金属氧化物Co3O4为研究的重点,采用水热法对其进行相应的制备,并利用XRD、SEM、EDS 对制备的材料采取了物相组成、形貌以及元素分布的表征测试,同时利用武汉科思特电化学工作站对制备材料采取超电容性能的测试分析。
简介:以粒径53~150μm的WC、Cr3C2(Cr3C2质量分数为10%~40%)和NiCrBSi粉末为原料,采用Stellite等离子转移弧(PTA)堆焊系统在45#钢基体上制备焊层。应用金相显微镜、X-射线衍射仪、扫描电镜、硬度计等设备分析焊层的结构和性能。结果表明:NiCrBSi自熔合金焊层组织由γ-(Ni,Fe)和其间弥散分布的CrB和(Cr,Fe,Ni)7C3相组成;Cr3C2加入后,焊层中出现Cr3C2衍射峰。随Cr3C2含量增加,焊层硬度、孔隙率和耐磨性逐渐提高,Cr3C2含量为30%时,硬度和耐磨性均达到峰值。铸造WC加入后,以WC、W2C为主,并有少量(Cr,Fe,Ni)7C3和(Ni,Cr,W)3C产生。Cr3C2含量为40%的Cr3C2焊层较Ni50A焊层耐磨性提高197.6%,比加入相同含量铸造WC焊层耐磨性提高97.6%。Cr3C2、铸造WC加入后,焊层的磨损机理不同:Cr3C2/Ni属于均匀磨损,WC/Ni属于非均匀磨损。
简介:TheShanghai2010WorldExpoorganizersignedcooperationdealsonOctober13withnineYangtzeDeltacities-Changzhou,Yangzhou,ZhenjiangandTaizhouinJiangsuProvince,andNantong,Huzhou,Jiaxing,ZhoushanandTaizhouinZhejiangProvince-forFriendshipDayduringExpo.YangXiong,ShanghaiExecutiveViceMayorandexecutivedeputydirectoroftheEx-